Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10562986 | PMC |
| http://dx.doi.org/10.1001/jama.2023.17134 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Coherent-Precipitation-Stabilized Phase Formation in Over-Stoichiometric Rocksalt-Type Li Superionic Conductors.
Adv Mater
December 2024
Department of Materials Science and Engineering, University of California, Berkeley, CA, 94720, USA.
Rationalizing synthetic pathways is crucial for material design and property optimization, especially for polymorphic and metastable phases. Over-stoichiometric rocksalt (ORX) compounds, characterized by their face-sharing configurations, are a promising group of materials with unique properties; however, their development is significantly hindered by challenges in synthesizability. Here, taking the recently identified Li superionic conductor, over-stoichiometric rocksalt Li-In-Sn-O (o-LISO) material as a prototypical ORX compound, the mechanisms of phase formation are systematically investigated.
View Article and Find Full Text PDFMechanically induced polyamorphism in a one-dimensional coordination polymer.
Chem Sci
January 2025
Department of Chemistry, Graduate School of Science, Kyoto University Kitashirakawa-Oiwakecho, Sakyo-ku Kyoto 606-8502 Japan
We created different amorphous structures of a coordination polymer by applying mechanical shear forces. One-dimensional Cu(TfN)(bip) (1, TfN = bis(trifluoromethanesulfonyl)imide, bip = 1,3-bis(1-imidazolyl)propane) melted at 245 °C and underwent a glass transition at -10 °C by a static cooling process. 1 formed another amorphous state with a distinct glass transition point of 70 °C under oscillatory shear stress.
View Article and Find Full Text PDFMonitoring and controlling zeolite synthesis reactor-based solutions: a fed-batch strategy.
React Chem Eng
November 2024
Center for Sustainable Catalysis and Engineering (CSCE), KU Leuven 3001 Leuven Belgium
Most conventional zeolite synthesis takes place in closed batch autoclaves that cannot be monitored or controlled during the process. Moreover, the study of time-dependent parameters of the synthesis with the conventional "cooling-opening" procedure not only reduces accuracy as a series of reactors (never 100% identical) needs to be started in parallel (and stopped at different times), it is also labor intense. Furthermore, the classic batch concept does not permit the intermediate addition of species without disrupting synthesis and the cooling-reheating effects.
View Article and Find Full Text PDFCovalent Organic Frameworks with Regulated Water Adsorption Sites for Efficient Cooling of Electronics.
ChemSusChem
November 2024
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, P. R. China.
The excessive heat accumulation has been the greatest danger for chips to maintain the computing power. In this paper, a passive thermal management strategy for electronics cooling was developed based on the water vapor desorption process of the covalent organic frameworks (COFs). The precise regulation for the number of carbonyl group and the ratio of hydrophilicity and hydrophobicity within pore channels was achieved by water adsorption sites engineering.
View Article and Find Full Text PDFChromosomal-Level Genome Suggests Adaptive Constraints Leading to the Historical Population Decline in an Extremely Endangered Plant.
Mol Ecol Resour
November 2024
State Key Laboratory of Biocontrol, Guangdong Provincial Key Laboratory of Plant Stress Biology, Innovation Center for Evolutionary Synthetic Biology, School of Life Sciences, Sun Yat-sen University, Guangzhou, China.
Article Synopsis
- Human activity and climate change have significantly threatened wild habitats, leading to many species, like Pellacalyx yunnanensis, nearing extinction due to exploitation and reduced genetic diversity.
- We assembled a detailed genome for P. yunnanensis, revealing its troubled evolutionary history marked by population size reductions and detrimental mutations, which may limit its ability to adapt to changing environments.
- Our research also uncovers the species' reproductive challenges due to the loss of seed dormancy, which hinders its survival under adverse conditions, and provides insights that could inform future conservation strategies.
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!