An in-syringe low-density solvent dispersive liquid-liquid microextraction (IS-LDS-DLLME) is presented for the extraction of palladium from a highly acidic medium before its quantification by inductively coupled plasma optical emission spectroscopy. The extraction solvent was 1-undecanol, and benzil mono-(2-pyridyl) hydrazone was employed as a ligand. Here, no dispersive solvent is needed as the vortex disperses 1-undecanol in the aqueous sample solution. The experimental variables pH, concentration of the ligand, type and quantity of the extraction solvent, vortex time, and addition of NaCl were optimized. The described approach has detection and quantification limits of 0.13 and 0.43 μg L, respectively, an enrichment factor of 91, a linear analytical range from 0.4 to 250 μg L, and a precision of 1.7-2.0 % (25.0 μg L). The approach was used to analyze electronic waste samples and certified reference material.
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