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Tailored PVDF Graft Copolymers via ATRP as High-Performance NCM811 Cathode Binders. | LitMetric

AI Article Synopsis

Article Abstract

High-nickel layered oxides, e.g., LiNiCoMnO (NCM811), are promising candidates for cathode materials in high-energy-density lithium-ion batteries (LIBs). Complementing the notable developments of modification of active materials, this study focused on the polymer binder materials, and a new synthetic route was developed to engineer PVDF binders by covalently grafting copolymers from poly(vinylidene fluoride--chlorotrifluoroethylene) (PVDF-CTFE) with multiple functionalities using atom transfer radical polymerization (ATRP). The grafted random copolymer binder provided excellent flexibility (319% elongation), adhesion strength (50 times higher than PVDF), transition metal chelation capability, and efficient ionic conductivity pathways. The NCM811 half-cells using the designed binders exhibited a remarkable rate capability of 143.4 mA h g at 4C and cycling stability with 70.1% capacity retention after 230 cycles at 0.5 C, which is much higher than the 52.3% capacity retention of nonmodified PVDF. The well-retained structure of NCM811 with the designed binder was systematically studied and confirmed by post-mortem analysis.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10548467PMC
http://dx.doi.org/10.1021/acsmaterialslett.3c00485DOI Listing

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