Ultralow pressure sensing and luminescence thermometry based on the emissions of Er/Yb codoped YMoO phosphors.

Dalton Trans

Universidad de La Laguna, Departamento de Física, MALTA - Consolider Team, IMN and IUdEA Apdo. Correos 456, E-38206, San Cristóbal de La Laguna, Santa Cruz de Tenerife, Spain.

Published: October 2023

Pressure and temperature are fundamental physical parameters, so their monitoring is crucial for various industrial and scientific purposes. For this reason, we developed a new optical sensor material that allows monitoring of both the physical parameters. The synthesized material exhibits upconversion (UC) emission of Er in the red and green spectral regions under NIR (975 nm) laser irradiation. These UC emissions are strongly temperature-dependent, allowing multimode temperature sensing, either based on the luminescence intensity ratio between thermal-coupled energy levels (TCLs) or non-thermal-coupled energy levels (NTCLs) of Er ions. Meanwhile, the luminescence lifetime of the S state of Er ions was used as the third temperature-dependent spectroscopic parameter, enabling multi-parameter thermal sensing. Moreover, the observed enhancement of laser-induced heating of the sample under vacuum conditions allows for the conversion of the luminescent thermometer into a remote vacuum sensor. The pressure variations in the system are correlated with changes in the band intensity ratio (525/550 nm) of Er TCLs, which are further applied for optical, contactless vacuum sensing. This is because of the light-to-heat conversion effect, which is greatly enhanced under vacuum conditions and manifests as a change in the intensity ratio of Er bands (525/550 nm). The obtained results indicate that an YMoO:Er/Yb (YMO) phosphor has great application potential for the development of multi-functional and non-invasive optical sensors of pressure and temperature.

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http://dx.doi.org/10.1039/d3dt02613bDOI Listing

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