Cork is a renewable and sustainable material, highly porous and lightweight. We valorised waste cork and recycled wine stoppers to make pyrolysed/carbonised solid cork, for use as economic and sustainable microwave (MW) absorbers at the microwave X-band (8-12 GHz), without binder or additives. Although cork is already a very lightweight material (0.16 g cm), the pyrolysed cork is five-times less dense at 0.031 g cm, was amorphous graphitic carbon, and had an excellent shielding effectiveness (SE) of -18 to -38 dB, depending on thickness, with attenuation of the electromagnetic energy through internal reflection within the cellular cork structure. Furthermore, this ultra-light-weight material has an extremely high MW specific shielding effectiveness or efficiency (SSE), between -640 to -1235 dB g cm over the entire X-band range, depending on thickness (3.0-8.6 mm), one of the highest reported for any pure carbon material, this upper value being more than twice that of any previously reported graphite-based foams.
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http://dx.doi.org/10.1039/d3nr04411d | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, P. R. China.
Gradient structures are effective for microwave absorbing but suffer from inadequate lightweight and poor flexibility, making them fall behind the comprehensive requirements of electromagnetic protection. Herein, we propose a hierarchical gradient structure by integration with porous and sandwich structures. Specifically, polyimide (PI) foams are used as a robust and flexible skeleton, in which the foam cell walls are sandwiched by TiCT, ZnO, and ZrO atomic layers in sequence.
View Article and Find Full Text PDFACS Omega
December 2024
School of Chemistry and Materials Science, Shanxi Normal University, Taiyuan 030031, P. R. China.
The increasing concern over the negative impact of electromagnetic radiation and interference on humans has led to a growing interest in microwave-absorbing materials that are cost-effective, have a wide frequency range, and have high efficiency. In this paper, an FeO nanoparticle/carbonized hemp fiber composite was successfully prepared using hemp fibers as the primary material and template. By carefully regulating the concentration of the iron nitrate impregnation solution, accurate loading of FeO nanoparticles onto the carbonized hemp fiber was achieved.
View Article and Find Full Text PDFJ Colloid Interface Sci
February 2025
State Key Laboratory of Solidification Processing, Shannxi Province Key Laboratory of Fiber Reinforced Light Composite Materials, Carbon/Carbon Composites Research Center, Northwestern Polytechnical University, Xi'an 710072, China. Electronic address:
Multifaceted balance makes the design of ceramics difficult but is urgently needed. This work purposes to grow uniform edge-rich graphene (ERG) on alumina (AlO/ERG) in-situ, then constructs a discontinuous conductive, strengthening and toughening network of crosslinked ERG by mixing AlO/ERG with AlO and sintering. Under the guarantee of the tight-bound covalent interface, ERG and doping AlO strengthen and toughen the ceramic by synergistic effect of weak and strong interface.
View Article and Find Full Text PDFHeliyon
November 2024
Peter The Great St. Petersburg Polytechnic University, Saint Petersburg, 195251, Russia.
Electromagnetic pollution, or electromagnetic interference (EMI), is a phenomenon that has arisen due to the fast spread of electronic gadgets. To overcome EMI problem, polymer-based composites have sparked considerable attention among researchers owing to their superior qualities. Hence, this work utilizes magnetite-modified graphene (MMG) filler with polyvinylidene fluoride (PVDF) polymer to form polymer composites in various proportions ranging from 2 to 10 wt% to study the EM properties in the X-band.
View Article and Find Full Text PDFFood Chem
February 2025
Department of Biosystems Engineering, College of Agriculture, Isfahan University of Technology, Isfahan 84156-83111, Iran.
A free-space dielectric arrangement with X-band coaxial-to-waveguide adapters was used to non-destructively assess shell egg quality. Scattering parameters in the microwave spectral range (8-12 GHz) were measured in reflectance and transmittance modes from eggs placed in three orientations. Partial least squares regression was applied to predict egg quality indices, including air cell height (ACH), yolk coefficient (YC), thick albumen height (TAH), Haugh unit (HU), and albumen pH.
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