If the charging state of the lithium-ion battery can be accurately predicted, overcharge and overdischarge of the battery can be avoided, and the service life of the battery can be improved. In order to improve the prediction accuracy of SOC, a prediction method combined with convolutional layer, multi-head attention mechanism and gated cycle unit is proposed to extract data feature information from different dimensions of space and time. Using the data set of the University of Maryland, we simulated the battery in real vehicle operating conditions at different temperatures (0 °C, 25 °C, 45 °C). The test results showed that the mean absolute error, root mean square error and maximum prediction error of the model were 0.53%, 0.67% and 0.4% respectively. The results show that the model can predict SOC accurately. At the same time, the comparison with other prediction models shows that the prediction accuracy of this model is the highest.
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http://dx.doi.org/10.1038/s41598-023-43858-5 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory, Pune, Maharashtra 411008, India.
Lithium-sulfur (Li-S) batteries face significant challenges, such as polysulfide dissolution, sluggish reaction kinetics, and lithium anode corrosion, hindering their practical application. Herein, we report a highly effective approach using a zinc phosphide (ZnP) bifunctional catalyst to address these issues. The ZnP catalyst effectively anchors lithium polysulfides (LiPSs), catalytically reactivates them, and enhances lithium-ion diffusion.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
School of Metallurgy and Environment, Central South University, Changsha, Hunan, 410083, P. R. China.
The practical applications of all-solid-state batteries (ASSBs) are hindered by poor Li kinetics in electrodes due to the inadequate contact between the cathode active materials (CAMs) and solid-state electrolytes (SSEs). Therefore, improving the contact interface between CAMs and SSEs is necessary to improve the cathodic Li kinetics by increasing the lithium-ion transport sites. To address this issue, sub-micrometer LiPSCl (SU-LPSC) particles of high specific areas were utilized to fabricate cathodes with high mass loading.
View Article and Find Full Text PDFChem Sci
January 2025
State Key Laboratory of Powder Metallurgy, Central South University Changsha 410083 P. R. China
In overcoming the barrier of rapid Li transfer in lithium-ion batteries at extreme temperatures, the desolvation process and interfacial charge transport play critical roles. However, tuning the solvation structure and designing a kinetically stable electrode-electrolyte interface to achieve high-rate charging and discharging remain a challenge. Here, a lithium nonafluoro-1-butanesulfonate (NFSALi) additive is introduced to optimize stability and the robust solid electrolyte interface film (SEI), realizing a rapid Li transfer process and the structural integrity of electrode materials.
View Article and Find Full Text PDFFront Robot AI
January 2025
School of Metallurgy and Materials, University of Birmingham, Birmingham, United Kingdom.
Introduction: The transition to electric vehicles (EVs) has highlighted the need for efficient diagnostic methods to assess the state of health (SoH) of lithium-ion batteries (LIBs) at the end of their life cycle. Electrochemical Impedance Spectroscopy (EIS) offers a non-invasive technique for determining battery degradation. However, automating this process in industrial settings remains a challenge.
View Article and Find Full Text PDFACS Omega
January 2025
Department of Chemical Technology, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand.
The development of stable, high-performance electrolytes is essential to addressing the safety concerns and limited lifespan caused by the thermal and chemical instability of traditional organic carbonate-based electrolytes in lithium-ion batteries (LIBs). This study examined the potential of mixed solvent systems, specifically ethyl methyl carbonate (EMC) and tetramethylene sulfone (TMS), to modify ion solvation and improve ionic conductivity in LIB electrolytes. Through molecular dynamics simulations, we investigated the solvation structure and transport properties of lithium ions (Li) in these solvent environments.
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