Enhanced TC degradation by persulfate activation with carbon-coated CuFeO: The radical and non-radical co-dominant mechanism, DFT calculations and toxicity evaluation.

Facing the constraints of critical agglomeration and poor reusability of CuFeO in catalytic applications, the feasibility of synthesizing a composite catalyst using carbon coating technology for efficient TC removal with enhanced PDS activity was investigated. The composite catalyst (CuFeO@C) can stimulate both radical (SO and HO•) and non-radical (O) pathways to dominate the catalytic reaction for removing 95.7% of the TC in 60 min. Meanwhile, the defective structure of the external carbon layer protected the internal CuFeO from excessive oxidation, allowing the CuFeO@C to maintain over 90% TC removal after 5 cycles with less interference from inorganic anions, demonstrating significant catalytic performance and satisfactory reusability. Finally, the DFT calculations and TEST evaluation were performed to discuss the structural properties of TC and its toxicity assessment during the whole degradation process, while three possible degradation pathways were proposed. Significantly, the carbon-coated composite catalysts of potential universal applicability for multi-pathway PDS activation offered an attractive new strategy for the effective degradation of antibiotic wastewater.