Wearable energy storage devices require high mechanical stability and high-capacitance flexible electrodes. In this study, we design a flexible supercapacitor electrode consisting of 1-dimensional carbon nanotubes (CNT), cellulose nanofibrils (CNF), and manganese dioxide nanowires (MnO NWs). The flexible and conductive CNT/CNF-MnO NWs suspension was first prepared via ultrasonic dispersion approach, followed by vacuum filtration and hot press to form the composite paper electrode. The morphological studies show entanglement between CNT and CNF, which supports the mechanical properties of the composite. The CNT/CNF-MnO NWs electrode exhibits lower resistance when subjected to various bending angles (-120-+120°) compared to the CNT/CNF electrode. In addition, the solid-state supercapacitor also shows a high energy density of 38 μWh cm and capacitance retention of 83.2% after 5000 cycles.
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http://dx.doi.org/10.3390/polym15183758 | DOI Listing |
Anal Chem
December 2024
School of Agricultural Engineering, Jiangsu University, Zhenjiang 212013, PR China.
Conventional wearable flexible sensing systems typically comprise three components: a flexible substrate that contacts the skin, a signal processing module, and a signal output module. These components function relatively independently, resulting in a complex system that lacks sufficient integration. Therefore, developing an integrated wearable flexible sensing system by combining the flexible substrate, the signal processing module, and the signal output module not only enhances performance and comfort, but also reduces manufacturing costs and the risk of failure.
View Article and Find Full Text PDFTalanta
December 2024
Electroanalytical Chemistry Laboratory, Faculty of Chemistry, University of Guilan, Namjoo Street, P.O. Box: 1914-41335, Rasht, Iran.
Glutathione (GSH) is a bioactive tripeptide with important physiological functions in animals, plants, and microorganisms. GSH participates in various biochemical reactions in vivo and is known for its antioxidant, anti-allergy, and detoxification properties. This study introduces an innovative photoelectrochemical (PEC) method for GSH detection, leveraging a fluorine-doped tin oxide (FTO) electrode enhanced by TiO nanoflowers and graphitic carbon nitride quantum dots (g-CNQDs).
View Article and Find Full Text PDFBioresour Technol
February 2025
Department of Environmental Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China. Electronic address:
H-mediated microbial electrosynthesis (MES) could run under a high current density, but the low solubility of H limited its performance. Reducing the H bubble size facilitates H gas-liquid mass transfer and it has been reported to be realized on superaerophobic electrodes. Therefore, we adopted a CoP nanowire-modified nickel foam (CoP-NiF) as the superaerophobic cathode in a H-mediated MES reactor to enhance the methane production from CO.
View Article and Find Full Text PDFACS Sens
November 2024
Technical Physics Division, Bhabha Atomic Research Centre, Mumbai 400085, India.
Surface functionalization of semiconducting metal oxides has emerged as a highly effective approach for enhancing their sensing capabilities. In the present work, the surface of randomly oriented zinc oxide (ZnO) nanowires is modified with an optimized thickness (7 nm) of magnesium oxide (MgO), which exhibits an exceptionally sensitive and selective behavior toward NO gas, yielding a response of approximately 310 for 10 ppm concentration at room temperature. The synergistic interplay between ZnO and MgO leads to a remarkable 20-fold improvement in sensor response compared to a pristine ZnO film and allows the detection of concentrations as low as 50 ppb.
View Article and Find Full Text PDFRSC Adv
October 2024
Universitat Rovira i Virgili, Microsystems Nanotechnologies for Chemical Analysis (MINOS), Departament d'Enginyeria Electronica Països Catalans, 26 43007 Tarragona Catalunya Spain.
This paper presents the fabrication of sensors based on tungsten trioxide nanowires decorated with osmium oxide nanoparticles using the aerosol-assisted chemical vapor deposition (AACVD) technique. This methodology allows the obtention of different osmium oxide decoration loadings on the tungsten oxide nanowires. The morphological and chemical characteristics; and the structural properties of the sensing layers of the sensors were studied using different techniques such as FESEM, HR-TEM, and ToF-SIMS.
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