MEPROS - Modular electron paramagnetic resonance operating software for multifunctional high-frequency EPR spectrometer.

J Magn Reson

Magneto-Optical and THz Spectroscopy, Central European Institute of Technology (CEITEC), Brno University of Technology (BUT), Czech Republic. Electronic address:

Published: October 2023

We present a software solution developed in LabVIEW for a home-built High-Frequency Electron Paramagnetic Resonance (HF-EPR) spectrometer. A modular approach was applied to control the spectrometer subsystems and simplify the adaptation to hardware changes during the development. The solution implements measuring procedures for conventional Continuous Wave EPR (CW-EPR), Frequency-Swept EPR (FS-EPR), and Two-Dimensional EPR (2D-EPR) mapping, which are relevant in different cases. The software's automation capabilities were tested in several trial measurements to obtain CW-EPR spectra of Silicon Carbide doped by vanadium (SiC + V) at various temperatures and microwave frequencies, multi-frequency spectra via 2D-EPR mapping, and dense FS-EPR data of a lithium phthalocyanine crystal rotated in a magnetic field. Several prospective modifications of the software are discussed in the conclusion. A modular character allows the easy re-use of code portions in other experimental setups. The spectrometer and the software are currently deployed and utilized in a laboratory of EPR spectroscopy at Central European Institute of Technology (CEITEC) in Brno, and data obtained by it has been already used in a number of publications.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.jmr.2023.107556DOI Listing

Publication Analysis

Top Keywords

electron paramagnetic
8
paramagnetic resonance
8
spectrometer software
8
2d-epr mapping
8
epr
5
mepros modular
4
modular electron
4
resonance operating
4
software
4
operating software
4

Similar Publications

Synthesis and characterization of allomelanin model from 1,8-dihydroxynaphthalene autooxidation.

Sci Rep

January 2025

Faculty of Biochemistry, Biophysics and Biotechnology, Department of Plant Physiology and Biochemistry, Jagiellonian University, Gronostajowa 7, 30-387, Kraków, Poland.

In this work a novel method for synthesis of 1,8-dihydroxynaphthalene melanin was presented, as well as the physicochemical properties, molecular structure, and characteristics of the pigment. The proposed synthesis protocol is simple and cost-effective with no enzymes or catalysts needed. The final product is not adsorbed on any surface, since the pigment is the result of autooxidation of 1,8-dihydroxynaphthalene.

View Article and Find Full Text PDF

Mechanism of oxygen vacancy engineering CoO/FeO regulated electrocatalytic reduction of nitrate to ammonia.

J Colloid Interface Sci

December 2024

College of Environment and Ecology, Hunan Agricultural University, Changsha 410128, PR China; Key Laboratory for Rural Ecosystem Health in the Dongting Lake Area of Hunan Province, Changsha 410128, PR China; Yuelushan Laboratory, Hongqi Road, Changsha, Hunan 410128, PR China. Electronic address:

To enhance the activity of the nitrate reduction reaction (NORR), the development of oxygen vacancies electrocatalysts is a promising approach for improving the efficiency of ammonia synthesis. However, the mechanism by which oxygen vacancies regulate NORR to ammonia remains poorly understood. In this study, a series of CoO/FeO composite catalysts derived from ZIF-67 containing oxygen vacancies (OVs) were synthesized to elucidate the role of OVs on the activity and selectivity of ammonia synthesis.

View Article and Find Full Text PDF

Permanent Electride Magnets Induced by Quasi-Atomic Non-Nucleus-Bound Electrons.

Adv Mater

January 2025

Department of Materials Science and Engineering, Yonsei University, Seoul, 03722, Republic of Korea.

Article Synopsis
  • Interstitial quasi-atomic electrons (IQEs) significantly influence the magnetism of crystalline electrides, with their own magnetic moments affected by nearby cations.
  • Weak spin-orbit coupling and limited interactions prevent these systems from achieving hard magnetism, presenting a challenge for stronger magnetic properties.
  • However, certain 2D electrides, like [ReC]·2e, exhibit permanent magnetism by creating a ferrimagnetic state and demonstrate high coercivity due to the interaction between Re-spin and IQE-spin lattices.
View Article and Find Full Text PDF
Article Synopsis
  • This study explored the antioxidative effects of green tea extract (GTE) and ethylenediaminetetraacetic acid (EDTA) in improving the oxidation resistance of oleogel made from high oleic soybean oil.
  • Adding 300 ppm of GTE notably reduced free radicals and lipid hydroperoxides, extending the lag phase of oxidation by 5 days.
  • A combination of 300 ppm GTE and 75 ppm EDTA showed a synergistic effect in slowing down oxidation, and using the oleogel instead of shortening improved the oxidative stability of cookies even without added antioxidants.
View Article and Find Full Text PDF

Intriguing magnetic and electronic behaviors in La and Ru doped Sr2IrO4.

J Phys Condens Matter

December 2024

Departmet of Physics(MMV), Banaras Hindu University, Varanasi, Varanasi, Uttar Pradesh, 221005, INDIA.

We report a detailed experimental study of the structural, magnetic and electrical properties of La and Ru doped (Sr1-x Lax)2Ir1-xRuxO4 (x= 0.05, 0.15).

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!