AI Article Synopsis

  • - Sulfide glasses, particularly LiPS, can have high ionic conductivity due to crystallization during annealing, with bromine (Br) addition enhancing this property and mimicking the structure of LiGePS.
  • - A structural transition to the β-phase can decrease ionic conductivity, indicating the importance of maintaining the right structural form for optimal performance.
  • - Our study used advanced X-ray diffraction and bond valence sum methods to show that adding Br helps create pathways for Li ion conduction, suggesting that controlling anion structures can improve Li-ion conductivity in these materials.

Article Abstract

Sulfide glasses can exhibit notable ionic conductivity because of annealing-associated crystallization. One well-known example is LiPS. Our research showed that adding bromine (Br) to LiPS sulfide glass results in a similar crystal structure and high ionic conductivity comparable to that of another compound LiGePS. This structure differs from the PS anion framework of LiPS. In addition, the ionic conductivity decreases owing to a structural transition to the β-phase. Herein, we present our findings on the local structure of LiPS sulfide glass and its crystallized glass ceramic with the addition of Br. This analysis relies on the pair distribution function analysis obtained from high-energy X-ray diffraction. Moreover, using the bond valence sum method, we verified that incorporating Br promotes the formation of Li ionic conduction pathways. Our results indicate that precise control over the anion molecular structure by introducing halogens holds promise for achieving high Li-ion conductivity.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10520000PMC
http://dx.doi.org/10.1038/s41598-023-43347-9DOI Listing

Publication Analysis

Top Keywords

ionic conductivity
12
ionic conduction
8
lips sulfide
8
sulfide glass
8
ionic
5
structural analysis
4
analysis ionic
4
conduction mechanism
4
mechanism sulfide-based
4
sulfide-based solid
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!