In this study, we synthesized three novel acrylic monomers with a cinnamate group. We then mixed each monomer with 2-hydroxyethyl methacrylate (HEMA) to prepare soft contact lenses through bulk polymerization. Fourier transform infrared (FT-IR) and UV spectral analyses confirmed that the cinnamate group in the polymer undergoes a photodimerization reaction via UV irradiation. After UV curing, the present lenses stably maintained their shapes even in a water-swollen state and showed significantly improved mechanical properties compared to conventional lenses manufactured using a cross-linking agent. These lenses showed slightly lower water contact angles than the conventional lenses, although the water content was slightly reduced. The present photodimerization cross-linking method was found to be useful in reducing the tearability of soft lenses.
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http://dx.doi.org/10.1021/acsomega.3c04489 | DOI Listing |
Eur Phys J E Soft Matter
January 2025
Center for Life Nano Science@La Sapienza, Istituto Italiano di Tecnologia, Viale Regina Elena 291, 00161, Rome, Italy.
Understanding the values and origin of fundamental physical constants, one of the grandest challenges in modern science, has been discussed in particle physics, astronomy and cosmology. More recently, it was realized that fundamental constants have a biofriendly window set by life processes involving motion and flow. This window is related to intrinsic fluid properties such as energy and length scales in condensed matter set by fundamental constants.
View Article and Find Full Text PDFBiomater Sci
January 2025
Research Institute for Biomimetics and Soft Matter, Fujian Provincial Key Laboratory for Soft Functional Materials Research, Department of Physics, College of Physical Science and Technology, Xiamen University, Xiamen 361005, China.
Nature-inspired superhydrophobic materials have attracted considerable interest in blood-contacting biomedical applications due to their remarkable water-repellent and self-cleaning properties. However, the interaction mechanism between blood components and superhydrophobic surfaces remains unclear. To explore the effect of trapped air on platelet adhesion, we designed four distinct hydrophobic titanium dioxide (TiO) nanostructures with different fractions of trapped air.
View Article and Find Full Text PDFAlzheimers Dement
December 2024
University of Virginia, Charlottesville, VA, USA.
Background: The microvasculature of the central nervous system (CNS), which delivers oxygen and nutrients and forms a critical barrier protecting the CNS, is deleteriously affected by both Alzheimer's Disease (AD) and Type 2 Diabetes (T2D). Previous studies have shown pericyte dropout and vessel constriction in brain capillaries in AD, while other studies have shown pericyte bridging and dropout in retinal capillaries in T2D. T2D patients have increased risk of AD, suggesting potentially related microvascular pathological mechanisms.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Graduate School of Engineering, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba, Chiba 263-8522, Japan.
Organic multilayer systems, which are stacked layers of different organic materials, are used in various organic electronic devices such as organic light-emitting diodes (OLEDs) and organic field-effect transistors (OFETs). In particular, OFETs are promising as key components in flexible electronic devices. In this study, we investigated how the inclusion of an insulating tetratetracontane (TTC) interlayer in ambipolar indigo-based OFETs can be used to alter the crystallinity and electrical properties of the indigo charge transport layer.
View Article and Find Full Text PDFThe widespread demand for battery-powered technologies has propelled the search for efficient and commercially viable electrode materials with fast-charging abilities. Reported herein is an MoS2-expanded graphite (EG) composite as a stable and high-rate lithium-ion battery (LIB) anode, delivering specific capacities of 796 mAh g-1 at 0.5 A g-1 and 320 mAh g-1 at 20 A g-1 over 400 cycles.
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