Copper(I)-catalyzed cycloaddition of substituted cyclohexenyl acetylenes with azido(per)fluoroalkanes afforded 4-cyclohexenyl-substituted -(per)fluoroalkylated 1,2,3-triazoles. Their rhodium(II)-catalyzed transannulation led to fused -(per)fluoroalkyl pyrroles and subsequent oxidation provided -(per)fluoroalkyl indoles.
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| http://dx.doi.org/10.1039/d3ob01415k | DOI Listing |
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