In accelerated bridge constructions, the 3D printing process, and structural retrofitting, the bond condition between concrete layers considerably affects their structural safety and functionality. Nondestructive tests can effectively and efficiently monitor these structures' bond conditions. This paper used the convolutional neural network (CNN) and multilayer perceptron (MLP) to estimate the bond strength of concrete layers based on vital ultrasound parameters. In this regard, ultrasound pulse velocity, attenuation, maximum amplitude, and energy loss of the ultrasound wave were assessed as the inputs of the machine learning models. The target was the bi-surface shear strength of the specimens. Two different approaches were considered to evaluate the energy loss of the wave 1) in the whole specimen and 2) at the bond zone, and the models based on each dataset's accuracy were compared. Parameters resulting from the second approach were more reliable and had better consistency with bond strength variation than the first one. Moreover, the ultrasonic parameters were investigated to determine the most sensitive ultrasound factor to the different bond treatments. Accordingly, attenuation was the most susceptible parameter toward the change of bond strength.
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http://dx.doi.org/10.1016/j.ultras.2023.107168 | DOI Listing |
Phys Chem Chem Phys
January 2025
Department of Chemistry, Dr. Harisingh Gour Vishwavidyalaya (A Central University), Sagar-470003, India.
In a recent communication (A. Shivhare, B. Dehariya, S.
View Article and Find Full Text PDFBeilstein J Org Chem
January 2025
Department of Chemistry, University of Rhode Island, 140 Flagg Rd, Kingston, RI 02881, USA.
The CFH group can act as a hydrogen bond donor, serving as a potential surrogate for OH or SH groups but with a weaker hydrogen bond donation ability. Here, we describe a series of CFH group-containing moieties that facilitate hydrogen bond interactions. We survey hydrogen bond donation ability using several established methods, including H NMR-based hydrogen bond acidity determination, UV-vis spectroscopy titration with Reichardt's dye, and H NMR titration using tri--butylphosphine oxide as a hydrogen bond acceptor.
View Article and Find Full Text PDFMicrosc Res Tech
January 2025
Department of Restorative and Prosthetic Dental Sciences, College of Dentistry, Dar Al Uloom University, Riyadh, Saudi Arabia.
Effect of different root canal irrigation regimes microbubble emulsion (MBE) via riboflavin photosensitizer (RFP), cerium oxide (CeO) nanoparticles (NPs), and Nd: YAP laser on antibacterial efficiency, microhardness (MH), smear layer (SL) removal efficacy, and push-out bond strength (PBS) of AH plus sealer to canal dentin. Sixty single-rooted teeth were selected, disinfected, and categorized into four groups based on the type of disinfection. Following disinfection, a pair of samples were randomly selected and visualized under scanning electron microscope (SEM) for SL evaluation.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu, 210094, China.
After cyclo-pentazolate anion, a 5/6 fused structure of N is constructed, and four novel nitrogen-rich ionic compounds are assembled on its basis. The results of the quantum calculations revealed an uneven distribution of electrons on cyclo-N , with significant charge density near the N5/N9 atoms and an ADCH charge of -0.425.
View Article and Find Full Text PDFLasers Med Sci
January 2025
Department of Preventive and Restorative Dentistry, Discipline of Endodontics, Araçatuba School of Dentistry, São Paulo State University - UNESP, Araçatuba, SP, Brazil.
Investigate the impact of antimicrobial photodynamic therapy (aPDT) using different photosensitizers (PSs) such as indocyanine green (IG), curcumin (CC), and methylene blue (MB), with or without intracanal application of calcium hydroxide (CH), on the push-out bond strength of glass-fiber posts (GFPs) to intraradicular dentin, the chemical composition of the root substrate, and the sealing of the adhesive interface across different thirds of intraradicular dentin. A total of 112 bovine teeth underwent biomechanical preparation and were divided into eight experimental groups (n = 14 each): Negative control with deionized water; positive control with deionized water + CH; IG group with indocyanine green and infrared laser; IG + CH group; CC group with curcumin and blue LED; CC + CH group; MB group with methylene blue and red laser; and MB + CH group. The push-out bond strength was measured using a universal testing machine (n = 8), and scanning electron microscopy characterized the fracture patterns.
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