Twisted pore aperture of MOF induced three-dimensional restricted sieving separation for CO and CH mixtures.

Sci Bull (Beijing)

State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong Univerisy, Tianjin 300387, China; School of Chemical Engineering and Technology, Tiangong University, Tianjin 300387, China. Electronic address:

Published: November 2023

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http://dx.doi.org/10.1016/j.scib.2023.09.008DOI Listing

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Article Synopsis
  • * A new double-walled network, [NiL(μ-HO)], featuring a unique azo linker and 8-connected building blocks, enables reversible transformations, increasing pore volume by 33%.
  • * The material demonstrates impressive gas uptake capacities, achieving 200 cm/cm for methane at high pressure, ranking among the top FMOMs for methane storage performance.
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