Construction of floatable flower-like plasmonic Bi/BiOCl-loaded hollow kapok fiber photocatalyst for efficient degradation of RhB and antibiotics.

The development of low-cost and high-efficiency photocatalysts for the degradation of organic pollutants has been an essential and feasible approach to environmental remediation. However, conventional powder photocatalysts suffer from agglomeration, limited light utilization, and reuse difficulties, which hinder their large-scale practical application. Herein, a floatable flower-like plasmonic Bi/BiOCl-loaded hollow kapok fiber (KF/Bi/BC) photocatalyst was synthesized by a facile solvothermal method. It exhibited excellent photocatalytic degradation of Rhodamine B (RhB), ofloxacin (OFX), and tetracycline (TC) under UV-vis irradiation. The incorporation of metallic Bi not only greatly enhanced the light absorption of BiOCl in the visible region but also served as an effective "electron trap", facilitating the efficient separation and transfer of photogenerated electrons and holes. Furthermore, the remarkable floatability of the catalyst contributed to increased light utilization and facilitated the recycling of the catalyst. This work provided a convenient, effective, and feasible method for the fabrication of floatable photocatalysts with excellent catalytic properties, and has great potential for practical applications.