Starting from the respective metal , we have synthesized the hexafluorides F of = Ru, Rh, and Pt by the use of a laser-based heating system and a remote fluorine plasma source using a mixture of Ar and NF as the feed gas. The formation of the hexafluorides was confirmed by several different spectroscopic methods, including IR, Raman, UV/vis, and NMR spectroscopy. In addition, we present first experimental hints that RuF is more reactive than PtF, because RuF is able to oxidize lower fluorides of platinum to PtF.
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Plasmachemical Syntheses of RuF, RhF, and PtF.
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Starting from the respective metal , we have synthesized the hexafluorides F of = Ru, Rh, and Pt by the use of a laser-based heating system and a remote fluorine plasma source using a mixture of Ar and NF as the feed gas. The formation of the hexafluorides was confirmed by several different spectroscopic methods, including IR, Raman, UV/vis, and NMR spectroscopy. In addition, we present first experimental hints that RuF is more reactive than PtF, because RuF is able to oxidize lower fluorides of platinum to PtF.
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