Flexible humidity sensors have found new applications in diverse fields including human healthcare, the Internet of Things, and so on. In this paper, a highly sensitive humidity sensor based on carboxymethyl cellulose@graphene and conductive adhesive tape was developed. The sensor was constructed on conductive tape which acted as both of the flexible substrate and the electrode to transmit electronic signals. A carboxymethyl cellulose@graphene composite was assembled on the substrate as the sensing layer by a simple spreading method in a 3-D printed groove mold. The sensitive material was characterized for its morphology, composition, crystalline phase, and hydrophilicity by SEM, EDS, XRD, and contact angle measurements. The effect of graphene on the sensitivity was investigated in detail by adjusting the doping concentration. Humidity sensing performance was tested in different relative humidity levels. The rapid responses under different respiratory conditions demonstrated their practical usability in continuous respiration monitoring and recognition of respiratory status. The conductive mechanism of the sensing film was studied by complex impedance spectroscopy under different relative humidity levels. A rational sensing mechanism was proposed integrating ionic conduction, electron conduction and swelling behavior of the carboxymethyl cellulose@graphene composite.
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http://dx.doi.org/10.1039/d3ra05232j | DOI Listing |
Int J Biol Macromol
January 2025
Institute of Engineering, Science, and Technology, Universidade Federal dos Vales do Jequitinhonha e Mucuri/UFVJM, Av. 01, 4050 Cidade Universitária, 39440-039 Janaúba, MG, Brazil; Pos-Graduate Program of Chemistry from Universidade Federal dos Vales do Jequitinhonha e Mucuri/UFVJM, Av. 01, 4050 Cidade Universitária, 39440-039 Janaúba, MG, Brazil. Electronic address:
The present research produced a new nanocomposite based on carboxymethyl cellulose (CMC) and graphene oxide (GO) for application in energy devices. A modified Hummers' method and two modifiers (UV radiation and heat temperature) were used. The nanocomposite was characterized by spectroscopies (FTIR, RAMAN, UV Vis), X-ray diffraction, morphological (SEM, TEM, DLS), and surface charge (ZP).
View Article and Find Full Text PDFInt J Biol Macromol
October 2024
Department of Chemistry, Division of Science and Technology, University of Education, College Road, Lahore, Pakistan. Electronic address:
Hydrogels are hydrophilic, insoluble, and highly porous 3D networks capable of absorbing large amounts of water. This study aimed to develop a carboxymethyl cellulose/graphene oxide (CMC/GO) hydrogel, cross-linked with citric acid and modified with zinc oxide (ZnO) nanoparticles (CMC/GO/ZnO), synthesized via the sol-gel method. The formulated composite hydrogel samples were characterized by Fourier transmittance infrared spectroscopy (FTIR), scanning electron microscopy (SEM) analysis, X-ray diffraction (XRD), transmission electron microscopy (TEM), and thermo-gravimetric analysis (TGA).
View Article and Find Full Text PDFInt J Biol Macromol
June 2024
Liaoning Key Lab of Lignocellulose Chemistry and BioMaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China. Electronic address:
Modulating the interactions between biopolymer matrix and nanofillers highly determined the mechanical performances of composite packaging materials. Herein, we innovatively proposed a sort of eco-friendly and mechanically robust carboxymethyl cellulose/graphene oxide/tannic acid/polyetherimide (CMC/GO/TA/PEI, CGTP) composite by employing PEI as cross-linker and TA as proton donor. The amidation reaction between -NH and -COOH chemically connected the CMC/GO, CMC/CMC and GO/GO and the physical interaction (e.
View Article and Find Full Text PDFIn this work, a signal amplification strategy was designed by the fabrication of a highly sensitive and selective electrochemical sensor based on nickel-copper-zinc ferrite (NiCuZnFeO)/carboxymethyl cellulose (CMC)/graphene oxide nanosheets (GONs) composite modified glassy carbon electrode (GCE) for determination of omeprazole (OMP). The one-step synthesized NiCuZnFeO/CMC/GONs nanocomposite was characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy and X-ray diffraction techniques. Then, the NiCuZnFeO/CMC/GONs/GCE was applied to study the electrochemical behavior of the OMP.
View Article and Find Full Text PDFFlexible humidity sensors have found new applications in diverse fields including human healthcare, the Internet of Things, and so on. In this paper, a highly sensitive humidity sensor based on carboxymethyl cellulose@graphene and conductive adhesive tape was developed. The sensor was constructed on conductive tape which acted as both of the flexible substrate and the electrode to transmit electronic signals.
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