Three-dimensional (3D) electrochemical oxidation has become a popular advanced oxidation technology for wastewater treatment due to its various benefits. In this study, cerium (Ce) loaded biochar (Ce/BC) was used as a particle electrode to conduct the degradation of industrial wastewater released by the chemical industry. SEM, EDS, XRD, FTIR, XPS, and BET were used to characterize the properties of Ce/BC. The effects of some variables, including Ce loading (0-5%), pH (5-9), Ce/BC dosage (12.5-50.0 g/L), and working voltage (12-20 V), were evaluated with regard to COD elimination. The kinetics of COD oxidation and the energy consumption were carefully investigated. Tert-butanol significantly reduced the removal efficiency of COD, indicating that hydroxyl radicals generated during the process rather than direct electro-oxidation were the main mechanism for COD degradation. The treatment of industrial wastewater might benefit from the use of Ce/BC as particle electrode.
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http://dx.doi.org/10.1080/09593330.2023.2260121 | DOI Listing |
Rev Sci Instrum
January 2025
College of Electrical Engineering and Control Science, Nanjing Tech University, Nanjing 211816, Jiangsu, China.
Nanosecond pulse power has many driving advantages in the dielectric barrier discharge (DBD) application field, including better discharge effect, higher discharge efficiency, and lower electrode temperature. A high-voltage pulse voltage power supply (HV-PVPS) with a multi-turn ratio linear pulse transformer (PT) based on Marx circuit and PT topologies are suitable for most DBD plasma applications with fewer expansion modules, lower cost, smaller volume, and higher reliability comparing with the all-solid-state Marx nanosecond pulse power supply. However, during the process of DBD driven by an HV-PVPS based on Marx and PT topologies, the PT is prone to magnetic core saturation, which limits the application for DBD.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
i-Lab & Printable Electronics Research Center, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences(CAS), Suzhou, 215123, P. R. China.
The conductivity of AgNWs electrodes can be enhanced by incorporating Ag grids, thereby facilitating the development of large-area flexible organic solar cells (FOSCs). Ag grids from vacuum evaporation offer the advantages of simple film formation, adjustable thickness, and unique structure. However, the complex 3D multi-component structure of AgNWs electrodes will exacerbate the aggregation of large Ag particles, causing the device short circuits.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, United States.
Aqueous sodium-ion batteries (SIBs) are gradually being recognized as viable solutions for large-scale energy storage because of their inherent safety as well as low cost. However, despite recent advancements in water-in-salt electrolyte technologies, the challenge of identifying anode materials with sufficient specific capacity persists, complicating the wider adoption of these batteries. This study introduces an innovative and straightforward approach for synthesizing vanadium oxide laser-scribed graphene (VO-LSG) composites, which function as effective anode materials in aqueous sodium-ion batteries.
View Article and Find Full Text PDFNano Lett
January 2025
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.
The transformation of bulk transition-metal dichalcogenide (TMD) particles into ultrathin nanosheets with both an acceptable yield and preserved crystalline integrity presents a substantial challenge in electrochemical exfoliation. This challenge arises from the continuous potential stress that the materials experience in traditional exfoliation setups. Herein, we propose a new fluidized electrochemical exfoliation (FEE) method to efficiently transform TMD powders into high-quality, few-layered TMD nanosheets in the aqueous phase.
View Article and Find Full Text PDFAnal Methods
January 2025
School of Pharmacy, Wannan Medical College, Wuhu 241002, China.
A label-free photoelectrochemical (PEC) sensor for detecting theophylline (TP) was exploited based on electrodes modified with a nanocomposite of polydopamine nanospheres (PDSs) and gold nanoparticles (AuNPs). PDS particles were prepared by oxidative autopolymerization, and their reducibility was utilized in one step to reduce the gold nanoparticles . The AuNPs-PDS/ZnS PEC sensor was constructed by electrochemical deposition and drop coating.
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