The Mpemba effect refers to the counterintuitive phenomenon of a hotter system equilibrating faster than a colder system when both are quenched to the same low temperature. For a Brownian particle trapped in a piecewise linear single well potential that is devoid of any other metastable minima, we show the existence of the Mpemba effect for a wide range of parameters through an exact solution. This result challenges the prevalent explanation of the Mpemba effect that requires the energy landscape to be rugged with multiple minima. We also demonstrate the existence of inverse and strong Mpemba effects.
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http://dx.doi.org/10.1103/PhysRevE.108.024131 | DOI Listing |
Entropy (Basel)
January 2025
Física Teórica, Universidad de Sevilla, Apartado de Correos 1065, E-41080 Sevilla, Spain.
Heat engines transform thermal energy into useful work, operating in a cyclic manner. For centuries, they have played a key role in industrial and technological development. Historically, only gases and liquids have been used as working substances, but the technical advances achieved in recent decades allow for expanding the experimental possibilities and designing engines operating with a single particle.
View Article and Find Full Text PDFEur Phys J E Soft Matter
January 2025
Université Paris-Saclay, CNRS, FAST, 91405, Orsay, France.
We study experimentally at the macroscopic and microstructure scale a dense suspension of non-Brownian neutrally buoyant spherical particles experiencing periodic reversals of flow at constant rate between parallel plates and tracked individually. We first characterize the quasi-steady state reached at the end of half periods. The volume fraction of particles increases from the walls to the center as a result of migration induced by the nonuniform strain rate.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
Research Center for Advanced Science and Technology, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, 153-8904, Tokyo, Japan; Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, 153-8505, Tokyo, Japan. Electronic address:
Phase separation, a fundamental phenomenon in both natural and industrial settings, involves the coarsening of domains over time t to reduce interfacial energy. While well-understood for simple viscous liquid mixtures, the physical laws governing coarsening dynamics in complex fluids, such as colloidal suspensions, remain unclear. Here, we investigate colloidal phase separation through particle-based simulations with and without hydrodynamic interactions (HIs).
View Article and Find Full Text PDFChaos
January 2025
Research Center for Computer Science and Information Technologies, Macedonian Academy of Sciences and Arts, Bul. Krste Misirkov 2, 1000 Skopje, Macedonia.
We study a pair of independent searchers competing for a target under restarts and find that introduction of restarts tends to enhance the search efficiency of an already efficient searcher. As a result, the difference between the search probabilities of the individual searchers increases when the system is subject to restarts. This result holds true independent of the identity of individual searchers or the specific details of the distribution of restart times.
View Article and Find Full Text PDFJ Chem Phys
January 2025
The Institute of Mathematical Sciences, C.I.T. Campus, Taramani, Chennai 600113, India.
We explore the role of activity in the occurrence of the Mpemba effect within a system of an active colloid diffusing in a potential landscape devoid of metastable minimum. The Mpemba effect is characterized by a phenomenon where a hotter system reaches equilibrium quicker than a colder one when both are rapidly cooled to the same low temperature. While a minimal asymmetry in the potential landscape is crucial for observing this effect in passive colloidal systems, the introduction of activity can either amplify or reduce the threshold of this minimal asymmetry, resulting in the activity-induced and suppressed Mpemba effect.
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