Particles anomalously diffusing in contact with a thermal bath are initially released from an asymptotically flat potential well. For temperatures that are sufficiently low compared to the potential depth, the dynamical and thermodynamical observables of the system remain almost constant for long times. We show how these stagnated states are characterized as non-normalizable quasiequilibrium (NNQE) states. We use the fractional-time Fokker-Planck equation (FTFPE) and continuous-time random walk approaches to calculate ensemble averages. We obtain analytical estimates of the durations of NNQE states, depending on the fractional order, from approximate theoretical solutions of the FTFPE. We study and compare two types of observables, the mean square displacement typically used to characterize diffusion, and the thermodynamic energy. We show that the typical timescales for transient stagnation depend exponentially on the value of the depth of the potential well, in units of temperature, multiplied by a function of the fractional exponent.
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http://dx.doi.org/10.1103/PhysRevE.108.024133 | DOI Listing |
Phys Rev E
August 2023
Department of Physics, PUC-Rio, Rua Marquês de São Vicente 225, 22451-900 Gávea, Rio de Janeiro, Brazil.
Particles anomalously diffusing in contact with a thermal bath are initially released from an asymptotically flat potential well. For temperatures that are sufficiently low compared to the potential depth, the dynamical and thermodynamical observables of the system remain almost constant for long times. We show how these stagnated states are characterized as non-normalizable quasiequilibrium (NNQE) states.
View Article and Find Full Text PDFEntropy (Basel)
January 2021
Department of Physics, Institute of Nanotechnology and Advanced Materials, Bar-Ilan University, Ramat-Gan 52900, Israel.
We investigate the overdamped Langevin motion for particles in a potential well that is asymptotically flat. When the potential well is deep as compared to the temperature, physical observables, like the mean square displacement, are essentially time-independent over a long time interval, the stagnation epoch. However, the standard Boltzmann-Gibbs (BG) distribution is non-normalizable, given that the usual partition function is divergent.
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