A new solid phase extraction sorbent developed based on cyanopropyl functionalized silica nanoparticles for organophosphorus pesticides determination.

In this work, a simple sol-gel approach was used for the preparation of cyanopropyl (CNPr) functionalized silica nanoparticles (SiO-CNPr) that tetraethoxysilane (TEOS) and cyanopropyltriethoxysilane (CNPrTEOS) used as precursors. This as-prepared SiO-CNPr nanoparticle sorbent was first characterized using FESEM, EDX, FTIR, TGA, and BET techniques. Then, the SiO-CNPr nanoparticle was applied as a new SPE sorbent for determining trace levels of OPPs in environmental water samples. To enhance the simultaneous extraction of non-polar or/and polar OPPs and to obtain the most efficient sorbent, several sol-gel synthesis parameters were studied. In addition, the effect of several effective parameters on SPE performance was investigated toward simultaneous extraction of non-polar or/and polar OPPs. Moreover, the figures of merit such as precision, linearity, LOQ, LOD, and recovery were evaluated for the sorbent. Finally, the designed SiO-CNPr SPE was used to determine OPPs in real water samples, and its extraction performance was compared to commercial cartridges based on cyanopropyl.