Employing numerical simulations, we provide an accurate insight into the heat transfer mechanism in the Rayleigh-Bénard convection of concentrated emulsions with finite-size droplets. We focus on the unsteady dynamics characterizing the thermal convection of these complex fluids close to the transition from conductive to convective states, where the heat transfer phenomenon, expressed in terms of the Nusselt number Nu, is characterized by pronounced fluctuations triggered by collective droplet motion [F. Pelusi , , 2021, (13), 3709-3721]. By systematically increasing the droplet concentration, we show how these fluctuations emerge along with the segregation of "extreme events" in the boundary layers, causing intermittent bursts in the heat flux fluctuations. Furthermore, we quantify the extension and the duration of the coherent droplet motion accompanying these extreme events a suitable statistical analysis involving the droplet displacements. We show how the increase in droplet concentration results in a power-law behaviour of the probability distribution function of and and how this outcome is robust at changing the analysis protocol. Our work offers a comprehensive picture, linking macroscopic heat transfer fluctuations with the statistics of droplets at the mesoscale.
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http://dx.doi.org/10.1039/d3sm00716b | DOI Listing |
Anal Chem
January 2025
School of Life Sciences, Key Laboratory of Space Bioscience & Biotechnology, Northwestern Polytechnical University, Xi'an 710072, China.
Lymphoma is a malignant cancer characterized by a rapidly increasing incidence, complex etiology, and lack of obvious early symptoms. Efficient theranostics of lymphoma is of great significance in improving patient outcomes, empowering informed decision-making, and driving medical innovation. Herein, we developed a multifunctional nanoplatform for precise optical imaging and therapy of lymphoma based on a new photosensitizer (1-oxo-1-benzoo[de]anthracene-2,3-dicarbonitrile-triphenylamine (OBADC-TPA)).
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Department of Physics, Washington State University, Pullman, WA 99163, USA.
This work aims to determine the mechanism of the photomechanical response of poly(Methyl methacrylate) polymer doped with the photo-isomerizable dye Disperse Red 1 using the non-isomerizable dye Disperse Orange 11 as a control to isolate photoisomerization. Samples are free-standing thin films with thickness that is small compared with the optical skin depth to assure uniform illumination and photomechanical response throughout their volume, which differentiates these studies from most others. Polarization-dependent measurements of the photomechanical stress response are used to deconvolute the contributions of angular hole burning, molecular reorientation and photothermal heating.
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January 2025
Faculty of Mechanics, University Politehnica of Timisoara, Piata Victoriei 2, 300006 Timisoara, Romania.
This study investigated silicone composites with distributed boron nitride platelets and carbon microfibers that are oriented electrically. The process involved homogenizing and dispersing nano/microparticles in the liquid polymer, aligning the particles with DC and AC electric fields, and curing the composite with IR radiation to trap particles within chains. This innovative concept utilized two fields to align particles, improving the even distribution of carbon microfibers among BN in the chains.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Institute of Electric Power Engineering, Czestochowa University of Technology, Armii Krajowej 17, 42-200 Czestochowa, Poland.
During the heat treatment of round steel bars, a heated charge in the form of a cylindrically formed bundle is placed in a furnace. This type of charge is a porous granular medium in which a complex heat flow occurs during heating. The following heat transfer mechanisms occur simultaneously in this medium: conduction in bars, conduction within the gas, thermal radiation between the surfaces of the bars, and contact conduction across the joints between the adjacent bars.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
School of Mechatronics Engineering, Harbin Institute of Technology, Harbin 150001, China.
C-UHTC is an ideal aerospace material because of its exceptional properties, but its machinability is facing great challenges. Electrical discharge machining (EDM) offers a potential solution, but its removal mechanism remains unclear, lacking reliable prediction tools to guide the actual production. This paper deeply explores the EDM removal mechanism of C-ZrB-SiC through single-pulse experiments, high-speed camera observations, and thermal-fluid coupling simulations, revealing key processes like heat transfer, phase transformation, molten pool dynamics, crater formation, and reinforcing phase effects.
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