The production of low-cost solid adsorbents for carbon dioxide (CO) capture has gained massive consideration. Biomass wastes are preferred as precursors for synthesis of CO solid adsorbents, due to their high CO adsorption efficiency, and ease of scalable low-cost production. This review particularly focuses on waste biomass-derived adsorbents with their CO adsorption performances. Specifically, studies related to carbon (biochar and activated carbon) and silicon (silicates and geopolymers)-based adsorbents were summarized. The impact of experimental parameters including nature of biomass, synthesis route, carbonization temperature and type of activation methods on the CO adsorption capacities of biomass-derived pure carbon and silicon-based adsorbents were evaluated. The development of various enhancement strategies on biomass-derived adsorbents for CO capture and their responsible factors that impact adsorbent's CO capture proficiency were also reviewed. The possible CO adsorption mechanisms on the adsorbent's surface were highlighted. The challenges and research gaps identified in this research area have also been emphasized, which will help as further research prospects.
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http://dx.doi.org/10.1016/j.chemosphere.2023.140173 | DOI Listing |
Chemistry
January 2025
East China University of Science and Technology, School of Material Science & Engineering, P.O. Box 289, 130 Meilong Rd., 200237, Shanghai, CHINA.
Silicon/carbon (Si/C) materials have achieved commercial applications as a solution to the problems of large volume expansion and short lifespan of silicon-based anodes in lithium-ion batteries. However, the potential risk of structural fracture and localized differences in surface adsorption properties lead to difficulties in maintaining the structural integrity of Si/C anodes using conventional binders during repeated lithiation/delithiation. Herein, an aqueous binder (PVA-g-M) based on polyvinyl alcohol (PVA) grafted methacrylic acid (MAA) obtained by self-emulsifyingemulsion polymerization is reported.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Department of Materials Science, Fudan University, Shanghai, 200433, China.
Currently, lithium-ion batteries (LIBs) are at the forefront of energy storage technologies. Silicon-based anodes, with their high capacity and low cost, present a promising alternative to traditional graphite anodes in LIBs, offering the potential for substantial improvements in energy density. However, the significant volumetric changes that silicon-based anodes undergo during charge and discharge cycles can lead to structural degradation.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Research Center of Nano Science and Technology, College of Sciences, Shanghai University, Shanghai 200444, China.
The interfacial reaction of a silicon anode is very complex, which is closely related with the electrolyte components and surface elements' chemical status of the Si anode. It is crucial to elucidate the formation mechanism of the solid electrolyte interphase (SEI) on the silicon anode, which promotes the development of a stable SEI. However, the interface reaction mechanism on the silicon surface is closely related to the surface components.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China.
Silicon (Si) is regarded as a promising anode material owing to its high specific capacity and low lithiation potential. The large volume change and the pulverization of silicon during the lithiation/delithiation process hinder its direct energy storage application. This review focuses on the electrospun silicon/carbon (Si/C) nanofiber anode materials for lithium-ion batteries for long-term stable energy storage.
View Article and Find Full Text PDFACS Omega
December 2024
Faculty UnB Planaltina, Materials Science Postgraduate Program, University of Brasília, Brasília, Federal District 73345-010, Brazil.
Two-dimensional (2D) silicon-based materials have garnered significant attention for their promising properties, making them suitable for various advanced technological applications. Here, we present Irida-Silicene (ISi), a novel 2D silicon allotrope inspired by Irida-Graphene (IG), which was recently proposed and is entirely composed of carbon atoms. ISi exhibits a buckled structure composed of 3-6-8 membered rings, unlike its planar carbon counterpart.
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