Modelling the flow properties of rubber blends makes it possible to predict their rheological behaviour during the processing and production of rubber-based products. As the nonlinear nature of such complex processes complicates the creation of exact analytical models, it is appropriate to use artificial intelligence tools in this modelling. The present study was implemented to develop a highly efficient artificial neural network model, optimised using a novel training algorithm with fast parallel computing to predict the results of rheological tests of rubber blends performed under different conditions. A series of 120 real dynamic viscosity-time curves, acquired by a rubber process analyser for styrene-butadiene rubber blends with varying carbon black contents vulcanised at different temperatures, were analysed using a Generalised Regression Neural Network. The model was optimised by limiting the fitting error of the training dataset to a pre-specified value of less than 1%. All repeated calculations were made via parallel computing with multiple computer cores, which significantly reduces the total computation time. An excellent agreement between the predicted and measured generalisation data was found, with an error of less than 4.7%, confirming the high generalisation performance of the newly developed model.
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http://dx.doi.org/10.3390/polym15173636 | DOI Listing |
J Phys Chem B
January 2025
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
Reline, which is composed of choline chloride and urea in a molar ratio of 1:2, is the first and most extensively studied deep eutectic solvent (DES). In certain applications, reline is blended with organic solvents, dimethyl sulfoxide (DMSO) in most cases, to gain improved properties. Therefore, it is crucial to have a profound understanding of the impact of DMSO on the dynamics and structures of the species in the binary mixtures.
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January 2025
Sustainable Polymer & Innovative Composite Materials Research Group, Department of Chemistry, Faculty of Science, King Mongkut's University of Technology Thonburi, Bangkok 10140, Thailand.
This study investigates the synergistic effects of incorporating modified zinc oxide-silica (ZnO-SiO) into tire waste (TW) and epoxidized natural rubber (ENR) blends, with a focus on crosslinking dynamics, mechanical reinforcement, and antibacterial activity. The addition of ZnO-SiO significantly enhanced crosslink density, as evidenced by increased torque and accelerated cure rates. An optimal concentration of 10 phr was found to yield the highest performance.
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December 2024
Department of Mechanical Engineering, PSG Institute of Technology and Applied Research Coimbatore, Coimbatore 641062, India.
In this work, twin-screw extruder and compression moulding techniques were utilized to fabricate polymer blends: polypropylene (PP), polybutadiene (PB), and composites using glass fibre (GF) and flax fibre (FF). During fabrication, the polymer ratios maintained between PP and PB were 90:10, 80:20, and 70:30. Likewise, the composites were fabricated by varying the ratios between the PP, PB, and GF, which were 90PP:10PB:10GF, 80PP:20PB:10GF, and 70PP:30PB:10GF.
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December 2024
Centro de Física de Materiales (CSIC-UPV/EHU)-Materials Physics Center (MPC), P. M. de Lardizábal 5, 20018 San Sebastián, Spain.
This work connects the calorimetric responses of different rubber-resin blends with varying resin contents with their alpha relaxation dynamics. We used differential scanning calorimetry and broadband dielectric spectroscopy to characterize the calorimetric and dielectric responses of styrene-butadiene, polybutadiene, and polyisoprene with different resin contents. To model the results, we used the Gordon-Taylor equation combined with an extension of the Adam-Gibbs approach.
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December 2024
Institute of Polymer and Dye Technology, Faculty of Chemistry, Lodz University of Technology, Stefanowskiego Street 16, 90-537 Lodz, Poland.
This study aimed to investigate the properties of tin(II) oxide (SnO) as an unconventional cross-linking agent for chloroprene (CR) and styrene-butadiene (SBR) rubbers compositions. The use of tin(II) oxide results from the need to reduce the use of zinc oxide as a cross-linking agent due to environmental regulations and its toxic impact on aquatic environments. The studied elastomeric blends can be cross-linked with tin(II) oxide, and the results demonstrate the significant potential of this oxide in such applications.
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