The increasing demand for rare earth elements (REEs), especially from new and innovative technology, has strained their supply, which makes the exploration of new REE sources necessary, for example, the recovery of REEs from phsophogypsum (PG). PG is a byproduct during the wet production of phosphoric acid, which is an attractive secondary resource for REEs due to a large amount of REEs locked in them. In most cases, REEs contained in PG are mainly encapsulated in the gypsum crystal, leading to a low leaching efficiency. Therefore, it is particularly important to use various methods to enhance the leaching of REEs from PG. In this review, we summarized and classified various enhanced leaching methods for the recovery of REEs from PG, and the advantages and disadvantages of different methods were compared. A joint method of recrystallization and RIL may be a promising enhanced leaching approach for the recovery of REEs from PG. Recrystallization could achieve both the complete REE release and simultaneous preparation of industrial materials with high value added, such as high-strength α-hemihydrate gypsum by phase transformation of PG, and the RIL technology could adsorb the releasing REEs and realize their efficient extraction. Such a combination appears to show significant advantages because of high REE recovery, as well as high value-added product preparation at low cost.
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http://dx.doi.org/10.3390/molecules28176284 | DOI Listing |
Chem Commun (Camb)
January 2025
School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P. R. China.
Neodymium iron boron (NdFeB) magnets are critical components in green energy technologies and have received increasing attention due to the limited availability of the raw materials, specifically rare earth elements (REEs). The supply risks associated with primary mining of RE ores, which have significant environmental impacts, underscore the necessity for recycling RE secondary resources. Waste NdFeB magnets, generated during manufacturing processes and recovered from end-of-life products, represent valuable RE secondary resources.
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December 2024
Slovenian National Building and Civil Engineering Institute, 1000 Ljubljana, Slovenia.
The increase in industrial waste generation presents a global problem that is a consequence of the needs of modern society. To achieve the goals of the EU Green Deal and to promote the concept of circular economy (CE), the valorization of industrial residues as secondary raw materials offers a pathway to economic, environmental, energetic, and social sustainability. In this respect, Al-containing industrial residues from alumina processing (red mud), thermal power plants (fly ash and bottom ash), and metallurgy (slag), as well as other industries, present a valuable mineral resource which can be considered as secondary raw materials (SRMs) with the potential to be used in construction, supporting the concept of circular economy.
View Article and Find Full Text PDFTalanta
December 2024
National Centre for Compositional Characterization of Materials (NCCCM), Bhabha Atomic Research Centre, Department of Atomic Energy, Hyderabad, 500 062, India.
A new and high performance polytetrafluoroethylene (PTFE) digestor was designed and fabricated in-house for the total dissolution of granite samples for the determination of technology-critical elements (TCEs) by inductively coupled plasma optical emission spectrometry (ICP-OES). Initially, the granite sample (∼0.25 g) was placed in the PTFE digestor and added 8 mL(v/v) of 20%HF+40%HCl+10%HNO acid mixture.
View Article and Find Full Text PDFData Brief
December 2024
Department of Mining Engineering, Faculty of Earth Technology and Energy, University of Trisakti, Jakarta 11450, Indonesia.
This article presented the data of REEs (Rare Earth Elements) analysis from exploitation of Bangka tin tailing, Indonesia. Nowadays, REEs have broad applications in modern industry such as computer memory, DVDs, rechargeable batteries, cell phones, catalytic converters, fluorescent lighting, negative ion generators, and much more. A 30 min.
View Article and Find Full Text PDFSci Total Environ
December 2024
LAQV-REQUIMTE - Associated Laboratory for Green Chemistry, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.
Acid mine drainage (AMD) nature, persistence and the considerable amount of toxic elements cause significant environmental damage. Traditional passive treatment systems typically focus on neutralizing AMD using limestone and removing common toxic metal(loid)s, and often overlook the recovery of economic and strategic elements (e.g.
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