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In the last few decades, reticular chemistry has grown significantly as a field of porous crystalline molecular materials. Scientists have attempted to create the ideal platform for analyzing distinct anions based on optical sensing techniques (chromogenic and fluorogenic) by assembling different metal-containing units with suitable organic linking molecules and different organic molecules to produce crystalline porous materials. This study presents novel platforms for anion recognition based on reticular chemistry with high selectivity, sensitivity, electronic tunability, structural recognition, strong emission, and thermal and chemical stability. The key materials for reticular chemistry, Metal-Organic Frameworks (MOFs), Zeolitic Imidazolate Frameworks (ZIFs), and Covalent-Organic Frameworks (COFs), and the pre- and post-synthetic modification of the linkers and the metal oxide clusters for the selective detection of the anions, have been discussed. The mechanisms involved in sensing are also discussed.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10487703 | PMC |
http://dx.doi.org/10.3390/ijms241713045 | DOI Listing |
ACS Appl Mater Interfaces
December 2024
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, School of Chemistry, Northeast Normal University, Changchun 130024, China.
Liposomes have attracted attention in biomedicine and pharmacy for their benefits including reduced toxicity, extended pharmacokinetics, and biocompatibility. However, their limitations include susceptibility to blood clearance, rapid disintegration, and lack of functionality, restricting their further applications. To address these challenges, inspired by the unique topological features of cyclic polymers and the specific binding property of the choline phosphate (CP) lipid, dipole-dipole interactions between CP molecules are utilized to create a detachable cyclic PEG-embedded CP liposome (d-cycPEG-lipo).
View Article and Find Full Text PDFAdv Mater
December 2024
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China.
Ammonium-ion supercapacitors (AISCs) offer considerable potential for future development owing to their low cost, high safety, environmental sustainability, and efficient electrochemical energy storage capabilities. The rapid and efficient charge-transfer process at the AISC can endow them with high capacitive and cycling stabilities. However, the prolonged intercalation/deintercalation of NH in layered and framework materials often results in the cleavage of the active sites and the deconstruction of the framework, which makes it difficult to achieve long-term stable energy storage while maintaining high capacitance in the electrode materials.
View Article and Find Full Text PDFAdv Mater
December 2024
King Abdullah University of Science and Technology (KAUST), Division of Physical Sciences and Engineering, Functional Materials Design, Discovery and Development Research Group (FMD3), Thuwal, 23955-6900, Kingdom of Saudi Arabia.
Here, the fundamental requirements are described for understanding and using topology tools in the design of porous materials, emphasizing the relationships between nets, metal-organic framework (MOF) structures, nodes, and building blocks. Common design approaches are discussed, highlighting prerequisites for the rational design of MOFs, such as those with simple pcu topology through the molecular building block approach, or axial-to-axial pillaring. The importance of highly connected nets and building units is emphasized for achieving structural predictability.
View Article and Find Full Text PDFInorg Chem
December 2024
Institute for Innovative Materials and Energy, School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China.
The electric conductivity and charge transport efficiency of metal-organic frameworks (MOFs) dictate the effective utilization of built-in redox centers and electrochemical redox kinetics and therefore electrochemical performance. Reticular chemistry and the tunable microcosmic shape of MOFs allow for improving their electric conductivity and charge transfer efficiency. Herein, we synthesized two Ni-MOFs (Ni-tdc-bpy and Ni-tdc-bpe) by the solvothermal reaction of Ni ions with 2,5-thiophenedicarboxylic acid (Htdc) in the presence of conjugated 4,4'-bipyridyl (bpy) and 1,2-di(4-pyridyl)ethylene (bpe) coligands, respectively.
View Article and Find Full Text PDFTalanta
December 2024
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Analysis and Testing Center, Department of Chemistry, Northeast Normal University, Changchun, Jilin Province, 130024, China. Electronic address:
The rapid development of accurate and point-of-care diagnostic tools for foodborne diseases has made a massive impact in global health. Salmonella typhimurium (S. typhimurium) exemplifies an enteric pathogen, being a gram-negative bacteria responsible for several gastrointestinal and systemic illnesses.
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