Shape-morphing structures that can reconfigure their shape to adapt to diverse tasks are highly desirable for intelligent machines in many interdisciplinary fields. Shape memory polymers are one of the most widely used stimuli-responsive materials, especially in 3D/4D printing, for fabricating shape-morphing systems. They typically go through a hot-programming step to obtain the shape-morphing capability, which possesses limited freedom of reconfigurability. Cold-programming, which directly deforms the structure into a temporary shape without increasing the temperature, is simple and more versatile but has stringent requirements on material properties. Here, we introduce grayscale digital light processing (g-DLP) based 3D printing as a simple and effective platform for fabricating shape-morphing structures with cold-programming capabilities. With the multimaterial-like printing capability of g-DLP, we develop heterogeneous hinge modules that can be cold-programmed by simply stretching at room temperature. Different configurations can be encoded during 3D printing with the variable distribution and direction of the modular-designed hinges. The hinge module allows controllable independent morphing enabled by cold programming. By leveraging the multimaterial-like printing capability, multi-shape morphing structures are presented. The g-DLP printing with cold-programming morphing strategy demonstrates enormous potential in the design and fabrication of shape-morphing structures.
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http://dx.doi.org/10.1038/s41467-023-41170-4 | DOI Listing |
ACS Appl Energy Mater
December 2024
Research Center for Materials, Architectures and Integration of Nanomembranes (MAIN), Chemnitz University of Technology, 09107 Chemnitz, Germany.
Transforming thin films into high-order stacks has proven effective for robust energy storage in macroscopic configurations like cylindrical, prismatic, and pouch cells. However, the lack of tools at the submillimeter scales has hindered the creation of similar high-order stacks for micro- and nanoscale energy storage devices, a critical step toward autonomous intelligent microsystems. This Spotlight on Applications article presents recent advancements in micro-origami technology, focusing on shaping nano/micrometer-thick films into three-dimensional architectures to achieve folded or rolled structures for microscale energy storage devices.
View Article and Find Full Text PDFMacromol Rapid Commun
December 2024
Eye Center, Affiliated Second Hospital, School of Medicine, Zhejiang University, Hangzhou, 310027, China.
Poly(N-isopropyl acrylamide) (PNIPAm)-based smart hydrogels are widely employed in emerging applications such as drug delivery and tissue engineering, because their lower critical solution temperature (LCST) is close to physiological conditions. However, the dense chain collapse during the thermo-responsive phase transition restricts water diffusion, resulting in limited volumetric change. Here, a pure PNIPAm hydrogel that achieves a large-scale volume transition by incorporating PNIPAm microgels, is presented.
View Article and Find Full Text PDFMater Horiz
December 2024
Department of Mechanical Engineering, Stony Brook University, Stony Brook, NY 11794, USA.
Soft actuators hold great promise for applications in biomimetic robots, artificial muscles, and drug delivery systems due to their adaptability in diverse environments. A critical aspect of designing thermally responsive soft actuators is to achieve spatially programmable actuation under a global thermal stimulus. Different local actuation behaviors can be encoded in one actuator to enable complex morphing structures for different tasks.
View Article and Find Full Text PDFSci Adv
December 2024
Centre for Innovative Structures, College of Civil Engineering, Nanjing Tech University, 211816, Nanjing, China.
ACS Appl Mater Interfaces
December 2024
State Key Laboratory of Robotics and Systems, Harbin Institute of Technology, Harbin 150001, China.
Through billions of years of evolution, small and microorganisms have come to possess distinctive shape-morphing abilities to live in complex fluid environments. However, fabricating milliscale programmable machines with shape-morphing ability often involves complicated architectures requiring arduous fabrication processes and multiple external stimuli. Here, milliscale programmable machines with reconfigurable structures and extensible sizes are proposed based on the sequential assembly of simple Janus disks at liquid surfaces.
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