We have developed an original blue-light mediated iron-catalyzed oxy-phosphinylation of activated alkenes by secondary phosphine oxides under air at room temperature. Various β-ketophosphine oxides were then obtained in 43-97 % isolated yields. Control experiments revealed that radical process is involved in the mechanism.
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Blue-Light Driven Iron-Catalyzed Oxy-phosphinylation of Activated Alkenes for β-Ketophosphine Oxide Synthesis.
Chemistry
December 2023
CNRS, ISCR UMR 6226, Univ. Rennes, F 35000, Rennes, France.
We have developed an original blue-light mediated iron-catalyzed oxy-phosphinylation of activated alkenes by secondary phosphine oxides under air at room temperature. Various β-ketophosphine oxides were then obtained in 43-97 % isolated yields. Control experiments revealed that radical process is involved in the mechanism.
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