We present a readily available calix[5]arene derived cavitand receptor that is stabilized in the closed cone conformer through intermolecular hydrogen bonding with methanol molecules. The receptor features a highly spherical aromatic surface that binds C and C fullerenes effectively, and the binding event can be regulated allosterically by the addition of methanol.
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http://dx.doi.org/10.1039/d3cc03780k | DOI Listing |
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