CoOOH with a highly negative CB band for visible-light-driven photocatalytic degradation of refractory organic pollutants in peroxymonosulfate system: Enhanced performance and multi-path synergetic mechanisms.

To date, cobalt ions/oxides were proven to be the best peroxymonosulfate (PMS) activator in the homogeneous/heterogeneous system. Interestingly, we found out that CoOOH with a narrow band gap (2.18 eV) and highly negative CB band (-1.73 eV) showed a good potential to be a visible-light-driven photocatalyst for PMS activation. The results turned out that the reaction rate constant of typical refractory contaminants in the Vis-CoOOH/PMS system was about 2-5 times higher than that in the Dark-CoOOH/PMS system. The photogenerated electron (e) and hole (h) can react with PMS, which significantly facilitates charge separation. Meanwhile, the e on the highly negative CB band can react with oxygen to generate O•, which simultaneously accelerates the cycle Co(III)/Co(II) to generate radicals (O•, •OH and SO•) and non-radical (O). As a result, multiple ROS was involved in the degradation of contaminants. Especially, O• with a longer half-life over O is identified as the dominant ROS, enhancing the utilization of radicals and the effective attack with contaminants. Therefore, this study first reports the great potential of CoOOH as a visible-light photocatalyst and reveals the multi-path mechanism of the synergistic visible-light-driven photocatalysis and PMS activation for removing refractory contaminants in wastewater.