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Sustainable synthesis of benzimidazole-based Schiff base using reusable CaAlO nanophosphors catalyst: Insights into metal(II) complexes and DNA interactions.
Nucleosides Nucleotides Nucleic Acids
January 2025
Department of PG Studies and Research in Environmental Science, Kuvempu University, Shankaraghatta, India.
This article presents a new and facile method for the synthesis of Schiff base compounds with a benzimidazole group using a low-cost and reusable calcium aluminate nanophosphorus catalyst (CaAlO). This approach avoids harmful solvents and reactants, supporting a more environmentally friendly synthesis process. The catalyst maintained its activity and heterogeneity over four cycles with minimal loss of efficiency.
View Article and Find Full Text PDFAn economical synthesis of benzodiazepines using ACT@IRMOF core-shell as a potential eco-friendly catalyst through the activated carbon of thymus plant (ACT).
Nanoscale Adv
December 2024
Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina University 6517838683 Hamadan Iran
Here, a straightforward design is employed to synthesize a nanocatalyst based on a carbon-activated modified metal-organic framework using the solvothermal method. This work presents a simple and practical approach for producing the activated carbon derived from the Thymus plant (ACT) modified with amine-functionalized isoreticular metal-organic framework-3 (IRMOF-3) to create an ACT@IRMOF-3 core-shell structure. Successful functionalization was confirmed through N adsorption isotherms, FT-IR, FE-SEM, TEM, EDS, elemental mapping, TGA, and XRD analysis.
View Article and Find Full Text PDFNewly Found Rat CD103 Dendritic Cells Represent a Highly Immunogenic Subpopulation of Type-2 Conventional Dendritic Cells, Corresponding to Known Dendritic Cell Subsets in Mice and Humans.
Immunology
January 2025
Anatomy, Dokkyo Medical University, Mibu, Tochigi, Japan.
Dendritic cells (DCs), the primary antigen-presenting cells, have traditionally been identified by CD103 molecules in rats, whereas mouse and human DCs are identified by CD11c molecules. However, this history does not preclude the existence of CD103 DCs in rats. To explore this possibility, we examined MHCII cells in rat spleen and thymus, identifying a novel population of CD103MHCIICD45RCD172a cells.
View Article and Find Full Text PDFInvestigation of mono-nuclear cobalt(II) complexes with a tri-dentate quinoxalyl-hydrazone ligand for their potential in biological research and interaction with ct-DNA.
Int J Biol Macromol
February 2025
Department of Chemistry, Faculty of Science, Sohag University, Sohag, -82534, Egypt; Department of Chemistry, College of Science, King Faisal University, P.O. Box 400, Al-Ahsa 31982, Saudi Arabia. Electronic address:
The condensing reaction of 2-hydroxy-1-naphthaldehyde with quinoxalyl-2-carbohydrazide resulted in synthesizing of a novel derivative of hydrazone quinoxalyl ligand (Hdpq). The bonding behavior between Hdpq and Co(II) ion was investigated in molar ratios of 1: 1 and 2: 1 to produce two different complexes, Codpq and Co(dpq), respectively. Their chemical structure was verified using several spectroscopic approaches.
View Article and Find Full Text PDFPharmacokinetics and tissue distribution of key sesquiterpene glycosides in Dendrobium nobile analyzed by UHPLC-Q-Trap-MS/MS.
J Chromatogr B Analyt Technol Biomed Life Sci
January 2025
Guizhou Engineering Research Center of Industrial Key-technology for Dendrobium Nobile, Joint International Research Laboratory of Ethnomedicine of Ministry of Education, Zunyi Medical University, Zunyi, Guizhou 551800, China. Electronic address:
Dendrobium nobile (D. nobile), a traditional herb known for its immunomodulatory and neuroprotective properties, contains characteristic alkaloids and sesquiterpene glycosides. While alkaloids have been extensively studied, research on sesquiterpene glycosides remains limited.
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