A trace side product from the reaction of [Mo(AsCMe)(CO)(η-CH)] with [Mn(THF)(CO)(η-CHMe)] was identified as the biarsolyl complex [Mn{μ-(AsCMe)}(CO)(CHMe)] on the basis of a strategic synthesis from [Mn(THF)(CO)(η-CHMe)] and the pre-formed and structurally characterised biarsolyl (AsCMe). Crystallographic and computational data for this first example of a biarsolyl complex and free biarsolyls are discussed in the context of those for free biarsolyls.
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Dalton Trans
September 2023
Research School of Chemistry, Australian National University, Canberra, ACT, Australia.
A trace side product from the reaction of [Mo(AsCMe)(CO)(η-CH)] with [Mn(THF)(CO)(η-CHMe)] was identified as the biarsolyl complex [Mn{μ-(AsCMe)}(CO)(CHMe)] on the basis of a strategic synthesis from [Mn(THF)(CO)(η-CHMe)] and the pre-formed and structurally characterised biarsolyl (AsCMe). Crystallographic and computational data for this first example of a biarsolyl complex and free biarsolyls are discussed in the context of those for free biarsolyls.
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