A versatile Co-catalyst-vitamin B (cobalamin)-can be photochemically reduced to its catalytically active Co(I) form under visible light irradiation, in the presence of MIL-125-NH(Ti) as a photocatalyst and utilized for the generation of alkyl radicals. The prior reduction of cobalamin to the Co(II) form is not required in this method.
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| http://dx.doi.org/10.1039/d3cc02941g | DOI Listing |
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