The structure of a platinum(II) complex containing (R)-(dimethylamino)ethylnapthyl and bis(diphenylphosphanyl)methane monosulfide ligands, namely, {(R)-1-[1-(dimethylamino)ethyl]napthyl-κN,C}[(diphenylphosphanylmethyl)diphenylphosphine sulfide-κP,S]platinum(II) hexafluoridoantimonate dichloromethane monosolvate, [Pt(CHN)(CHPS)][SbF]·CHCl, was determined. The structural features are compared with analogous platinum bis(diphenylphosphanyl)methane monoxide [dppm(O)] and bis(diphenylphosphanyl)methane monoselenide [dppm(Se)] complexes in relation to their potential hemilability and stereochemical nonrigidity.
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Hemilability and structural considerations in complexes of platinum(II) comprising bis(diphenylphosphanyl)methane monoxide, monosulfide, and monoselenide.
Acta Crystallogr C Struct Chem
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Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut 06520-8107, USA.
The structure of a platinum(II) complex containing (R)-(dimethylamino)ethylnapthyl and bis(diphenylphosphanyl)methane monosulfide ligands, namely, {(R)-1-[1-(dimethylamino)ethyl]napthyl-κN,C}[(diphenylphosphanylmethyl)diphenylphosphine sulfide-κP,S]platinum(II) hexafluoridoantimonate dichloromethane monosolvate, [Pt(CHN)(CHPS)][SbF]·CHCl, was determined. The structural features are compared with analogous platinum bis(diphenylphosphanyl)methane monoxide [dppm(O)] and bis(diphenylphosphanyl)methane monoselenide [dppm(Se)] complexes in relation to their potential hemilability and stereochemical nonrigidity.
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