The synthesis of heteroleptic Cu(I) complexes with coumarin-functionalized aminodiphosphine and diimine ligands is described. The complexes show yellow to deep-red phosphorescence in the solid state at ambient temperature with quantum yields up to 21%. The emission color of the complexes can be tuned by systematic modifications in the ligand system.
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Heteroleptic copper(I) complexes with coumarin-substituted aminodiphosphine and diimine ligands: synthesis and photophysical studies.
Dalton Trans
September 2023
Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, 76131, Karlsruhe, Germany.
The synthesis of heteroleptic Cu(I) complexes with coumarin-functionalized aminodiphosphine and diimine ligands is described. The complexes show yellow to deep-red phosphorescence in the solid state at ambient temperature with quantum yields up to 21%. The emission color of the complexes can be tuned by systematic modifications in the ligand system.
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