Photocatalytic membranes can effectively integrate membrane separation and photocatalytic degradation processes to provide an eco-friendly solution for efficient water purification. It is of great significance to develop highly efficient photocatalytic membranes driven by visible light to ensure the long-term stability of membrane separation systems and the maximum utilization of solar energy. Metal-organic framework (MOF) is an emerging photocatalyst with a well-defined structure and tunable chemical properties, showing a broad application prospect in the construction of high-performance photocatalytic membranes. Herein, this work provides a comprehensive review of recent advancements in MOF-based photocatalytic membranes. Initially, this work outlines the main tailoring strategies that facilitate the enhancement of the photocatalytic activity of MOF-based photocatalysts. Next, this work introduces commonly used methods for fabricating MOF-based photocatalytic membranes. Subsequently, this work discusses the application and mechanisms of MOF-based photocatalytic membranes toward organic pollutant degradation, metal ion removal, and membrane fouling mitigation. Finally, challenges in developing MOF-based photocatalytic membranes and their practical applications are presented, while also pointing out future research directions toward overcoming these existing limitations.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/smll.202305066 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Construction of Self-Cleaning Membrane Integrating Underwater Superoleophobicity, Photocatalysis, and Antibacterial Activity for Water Purification.
Langmuir
January 2025
College of Light Industry and Materials, Chengdu Textile College, Chengdu, Sichuan 610039, China.
The treatment of oily wastewater and oil/water mixtures has received more and more attention. In this study, a Zn-MOF (ZIF-8) decorated polyimide (PI) nanofiber membrane with triple self-cleaning performance was constructed, and the decoration of ZIF-8 on the PI membrane improved the hydrophilicity of the composite membrane, which further enhanced the underwater oil resistance, and the mechanical properties of the membranes improved significantly with the increase of in situ growth time. In addition, the inherent photocatalytic and antibacterial properties of ZIF-8 endowed the membranes with fantastic performance.
View Article and Find Full Text PDFSemiconductor photocatalytic antibacterial materials and their application for bone infection treatment.
Nanoscale Horiz
January 2025
State Key Laboratory of Precision Manufacturing for Extreme Service Performance, College of Mechanical and Electrical Engineering, Central South University, Changsha 410083, China.
Bacterial infection in bone tissue engineering is a severe clinical issue. Traditional antimicrobial methods usually cause problems such as bacterial resistance and biosecurity. Employing semiconductor photocatalytic antibacterial materials is a more controlled and safer strategy, wherein semiconductor photocatalytic materials generate reactive oxygen species under illumination for killing bacteria by destroying their cell membranes, proteins, DNA, In this review, P-type and N-type semiconductor photocatalytic materials and their antibacterial mechanisms are introduced.
View Article and Find Full Text PDFThe photo-electrocatalytic property of hollow mesoporous graphene oxide/tungsten trioxide/titanium dioxide membrane photo-anode.
Heliyon
January 2025
College of Chemical Engineering, Zhejiang University of Technology, China.
Titania (TiO) is one of promising photo catalysts for its high ability to resistant photo corrosion and environmental friendliness, but its photocatalytic activity is too low to be used in industry. To find an approach to solve this problem, graphene oxide (GO), tungsten trioxide (WO) and TiO composite with hollow mesoporous structure was prepared by a two-step spray drying method. The composite was used as raw material to constitute a membrane onto ITO glass to form a membrane photo-anode.
View Article and Find Full Text PDFPhotocatalytic Organic Semiconductor-Bacteria Imprinted Polymers for Highly Selective Determination of at the Single-Cell Level.
Anal Chem
January 2025
Shandong Key Laboratory of Healthy Food Resources Exploration and Creation, School of Food Sciences and Engineering, State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China.
This work utilized a combination of photocatalytic organic semiconductors and bacteria to create a photocatalytic organic semiconductor-bacterial biomixture system based on a bacteria imprinted polymers (OBBIPs-PEC) sensor, for the detection of with high sensitivity in "turn-on" mode at the single-cell level. This outstanding sensor arises from an integration of two different types of semiconductor materials to form heterojunctions. As well this sensor involves combining a semiconductor material with cationic side chains and an electron transport chain within a natural cellular environment, in which the cationic side chain of poly(fluorene--phenylene) organic semiconductor at 2-(4-mesyl-2-nitrobenzoyl)-1,3-cyclohexanedione (PFP-OC@MNC) demonstrated the ability to penetrate the cell membrane of and interact with specific binding sites through electrostatic interactions.
View Article and Find Full Text PDFSolar-based technologies for removing potentially toxic metals from water sources: a review.
Environ Sci Pollut Res Int
January 2025
Departamento de Ciência E Tecnologia de Alimentos, Universidade Federal de Santa Catarina, Rod. Admar Gonzaga, 1346, Itacorubi, Florianópolis, Santa Catarina, 88034-001, Brazil.
Technological advances have led to a proportional increase in the deposition of contaminants across various environmental compartments, including water sources. Heavy metals, also known as potentially toxic metals, are of particular concern due to their significant harmful impacts on environmental and human health. Among the available methods for mitigating the threat of these metals in water, solar radiation-based technologies stand out for their cleanliness, cost-effectiveness, and efficiency in removing or reducing the toxicity of heavy metals.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!