Flame curtain kilns have emerged as the preferred biochar technology for smallholders but reported methane emissions (30 g kg biochar) have impeded carbon certification. Here, for flame curtain kilns we show almost no methane (0-3.6 g kg biochar) emissions for dry (<15 % moisture) feedstock consisting of twigs and leaves. Wet feedstock (>40 % moisture) however generated significant methane (>500 g kg biochar), underscoring that feedstock preparation is decisive for the carbon balance. Even for dry feedstock, both aerosol and CO emissions were significant (21-82 and 40-118 g kg biochar, respectively). The data demonstrate that certification of low-tech biochar made from dry twigs and leaves should not be objected to on the grounds of methane. Careful selection of feedstock and potential after-combustion of the syn-gases are probably needed to avoid CO and aerosol emissions. More data are needed on methane emissions of other dry feedstocks.
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http://dx.doi.org/10.1016/j.scitotenv.2023.166547 | DOI Listing |
Polymers (Basel)
July 2024
Faculty of Mechanical Engineering and Design, Kaunas University of Technology, Studentu Str. 56, LT-51424 Kaunas, Lithuania.
Jute is an inherent lignocellulosic fiber, consisting of hemicellulose, α-cellulose, and lignin. Industrial ventilation, automotive composites, upholstery, carpets, military uniforms, hospital furnishings, and curtains necessitate the integration of flame-retardance properties into jute fibers. In this investigation, seven weave-structured jute fabrics were treated using an organophosphorus-based flame-retardant (FR) chemical (ITOFLAM CPN) and a crosslinking agent (KNITTEX CHN) by the pad-dry-cure method.
View Article and Find Full Text PDFTris(1-aziridinyl)phosphine oxide (APO) used as flame retardant in textile products, such as curtains, carpets, and sleeping clothes, is prohibited in Japan under the "Act on the Control of Household Products Containing Harmful Substances." This study developed a GC-MS-based method to quantify APO more accurately and safely than the current official method. The APO in textile products was extracted with methanol, the extract was replaced with acetone instead of hexane as previously reported, and purified by florisil cartridge column.
View Article and Find Full Text PDFBig Box biochar kilns are an alternative to open pile burning that allows for in-woods biochar production in a simple metal box with no moving parts. This approach is based on technology used by charcoal makers for centuries but with a modern, mechanized approach. A mini-excavator or other piece of machinery is used to load, tend, and empty the kilns.
View Article and Find Full Text PDFSci Total Environ
December 2023
Universidad Cientifica del Sur (UCSUR), Lima, Peru. Electronic address:
Flame curtain kilns have emerged as the preferred biochar technology for smallholders but reported methane emissions (30 g kg biochar) have impeded carbon certification. Here, for flame curtain kilns we show almost no methane (0-3.6 g kg biochar) emissions for dry (<15 % moisture) feedstock consisting of twigs and leaves.
View Article and Find Full Text PDFSci Total Environ
February 2023
School of Geography, Earth and Environmental Sciences, University of Birmingham, Edgbaston, West Midlands B15 2TT, United Kingdom; Queensland Alliance for Environmental Health Sciences (QAEHS), The University of Queensland, 20 Cornwall Street, Woolloongabba, QLD 4103, Australia.
Concentrations of the chlorinated organophosphate esters (Cl-OPEs): tris(2-chloroethyl) phosphate (TCEP), tris(1-chloro-2-propyl) phosphate (TCIPP), and tris(1,3-dichloro-2-propyl) phosphate (TDCIPP) were measured in 273 waste synthetic foam and fabric articles collected in Ireland between 2019 and 2020. Articles examined comprised: polystyrene building insulation foam, as well as foam fillings and fabric coverings from furniture, mattresses, end-of-life vehicles, curtains, and carpets. Cl-OPEs were also measured in 156 samples from the same categories (except for building insulation foam) collected in 2015-16.
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