Retarding Effect of Hemp Hurd Lixiviates on the Hydration of Hydraulic and CSA Cements.

Wood wool panels are widely used in the construction industry as sustainable cementitious composites, but there is a growing need to replace traditional Portland cement with a binder that has a lower embodied carbon footprint. In addition, the sustainability of these panels may face serious impediments if the required amount of wood for their production needs a harvest rate higher than the rate at which the tree sources reach maturity. One solution is to use the wooden part of fast-growing plants such as hemp. However, the compounds extracted from the mixture of plants and water are the main cause of the delay observed during the hydration process of hydraulic binders in these cementitious composites. The objective of this study is to evaluate the effect of bio-aggregate lixiviates (hemp hurd) on the hydration kinetics of calcium sulfoaluminate (CSA) cement as a low-embodied-carbon alternative to ordinary Portland cement (OPC). The isothermal calorimeter showed that the hemp hurd lixiviate caused a greater delay in GU's hydration process than CSA's. At a 5% concentration, the main hydration peak for GU cement emerged after 91 h, whereas for CSA cement, it appeared much earlier, at 2.5 h. XRD and TGA analysis showed that after 12 h of hydration, hydration products such as calcium silicate hydrates (C-S-H) and portlandite (CH) were not able to form on GU cement, indicating low hydration of silicate products. Moreover, at 5% concentration, the carbonation of ettringite was observed in CSA cement. The compressive strength values obtained from the mixes containing hemp hurd lixiviate consistently showed lower values compared to the reference samples prepared with distilled water. Furthermore, the CSA samples demonstrated superior compressive strength when compared to the GU samples. After 28 days of hydration, the compressive strength values for CSA cement were 36.7%, 63.5% and 71% higher than GU cement at a concentration of 0.5%, 2% and 5% hemp hurd lixiviate, respectively.