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Large Phase-Transition Temperature Enhancement Achieved in a Layered Lead Iodide Hybrid Crystal by H/F Substitution. | LitMetric

Large Phase-Transition Temperature Enhancement Achieved in a Layered Lead Iodide Hybrid Crystal by H/F Substitution.

Inorg Chem

Ordered Matter Science Research Center, Nanchang University, Nanchang 330031, People's Republic of China.

Published: September 2023

AI Article Synopsis

Article Abstract

Organic-inorganic hybrid metal halides with structural flexibility and solution processability have been widely investigated for different application scenarios. However, the effective construction of phase-transition materials with a high phase-transition temperature () for potential practical applications remains a great challenge, and reports on the regulation of with significant enhancement have been rare. In this manuscript, we have realized a large increase of 148 K in a layered hybrid lead iodide crystal (4-FTMBA)PbI (4-FTMBA = 4-fluoro--trimethylbenzenaminium) by the H/F substitution strategy. Compared to the parent (TMBA)PbI (TMBA = -trimethylbenzenaminium), H/F substitution preserves the structural framework and crystal symmetry in (4-FTMBA)PbI. The introduction of heavier fluorine will significantly increase the motion barrier for the order-disorder transition, resulting in the remarkably improved . Temperature-dependent crystal structures, Raman spectra, and dielectric analyses well support the phase-transition behavior. In addition, evident thermochromism with a tunable direct band gap in (4-FTMBA)PbI has been observed using UV-vis spectra. To the best of our knowledge, the achieved enhancement of 148 K by H/F substitution is the highest among the organic-inorganic hybrid lead halide phase-transition materials. This finding would greatly inspire the rational design of functional materials with high performance.

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Source
http://dx.doi.org/10.1021/acs.inorgchem.3c02485DOI Listing

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