The group 7 complexes [M(κ-2,6-(RPO)CHN)(CO)L][BAr] [M = Mn, R = Pr, L = THF; M = Re, R = Bu, L = vacant site] undergo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BAr] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10484290 | PMC |
| http://dx.doi.org/10.1039/d3cc03201a | DOI Listing |
Publication Analysis
Top Keywords
lattice adaptivity
4
adaptivity triggered
4
triggered solid-gas
4
solid-gas reactions
4
reactions cationic
4
cationic group
4
group pincer
4
pincer complexes
4
complexes group
4
group complexes
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!