Quantum Dot-Based Fluorometric Sensor for Hg(II) in Water Customizable for Onsite Visual Detection.

An easy naked-eye detection technique for mercuric ions in water using silanized quantum dots is demonstrated. Cadmium selenide quantum dots were synthesized and rendered water soluble by silica overcoating. The quantum dot emission was instantly turned off by the mercuric ions in the analyte, enabling visual detection. The emission quenching was associated with a concomitant bathochromic shift, both in the absorption and emission profiles. The underlying mechanism is a permanent surface modification of quantum dots by mercuric ions, altering the electronic structure and, in turn, the photophysical properties. The results confirmed the potential of this simple system to be customized for on-site visual detection of mercury contamination in water bodies, biological fluids, and soil with high selectivity and sensitivity.