AI Article Synopsis
- Hydrogen bonding is really important in chemistry and helps scientists build things like polymers and cages.
- Researchers use X-ray tests to see how these structures look, but it's tricky because hydrogen atoms are not easily seen.
- The text talks about what we can learn from these tests, the problems they have, and new methods that could help scientists see hydrogen bonds better.
Article Abstract
Hydrogen bonding interactions are ubiquitous across the biochemical and chemical sciences, and are of particular interest to supramolecular chemists. They have been used to assemble hydrogen bonded polymers, cages and frameworks, and are the functional motif in many host-guest systems. Single crystal X-ray diffraction studies are often used as a key support for proposed structures, although this presents challenges as hydrogen atoms interact only weakly with X-rays. In this , we discuss the information that can be gleaned about hydrogen bonding interactions through crystallographic experiments, key limitations of the data, and emerging techniques to overcome these limitations.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d3cs00516j | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
High-Pressure Polymerization of Phenol toward Degree-4 Carbon Nanothread.
Nano Lett
January 2025
Center for High Pressure Science and Technology Advanced Research, Beijing 100193, P. R. China.
Saturated sp-carbon nanothreads (CNTh) have garnered significant interest due to their predicted high Young's modulus and thermal conductivity. While the incorporation of heteroatoms into the central ring has been shown to influence the formation of CNTh and yield chemically homogeneous products, the impact of pendant groups on the polymerization process remains underexplored. In this study, we investigate the pressure-induced polymerization of phenol, revealing two phase transitions occurring below 0.
View Article and Find Full Text PDFUntangling the role of single-atom substitution on the improvement of the hydrogen evolution reaction of YNS MXene in acidic media.
Phys Chem Chem Phys
January 2025
Departamento de Física Aplicada - Instituto de Ciencia de Materiales, Matter at High Pressure (MALTA) Consolider Team, Universidad de Valencia, Edificio de Investigación, C/Dr Moliner 50, Burjassot, 46100, Valencia, Spain.
The production of hydrogen (H) fuel through electrocatalysis is emerging as a sustainable alternative to conventional and environmentally harmful energy sources. However, the discovery of cost-effective and efficient materials for this purpose remains a significant challenge. In this study, we explore the potential of the transition-metal-substituted YNS MXene as a promising candidate for hydrogen production through the hydrogen evolution reaction (HER).
View Article and Find Full Text PDFConstant di/dz scanning tunneling microscopy: Atomic precision imaging and hydrogen depassivation lithography on a Si(100)-2 × 1:H surface.
Rev Sci Instrum
January 2025
Erik Jonsson School of Engineering and Computer Science, The University of Texas at Dallas, Richardson, Texas 75080, USA.
We introduce a novel control mode for Scanning Tunneling Microscope (STM) that leverages di/dz feedback. By superimposing a high-frequency sinusoidal modulation on the control signal, we extract the amplitude of the resulting tunneling current to obtain a di/dz measurement as the tip is scanned over the surface. A feedback control loop is then closed to maintain a constant di/dz, enhancing the sensitivity of the tip to subtle surface variations throughout a scan.
View Article and Find Full Text PDFLaser Synthesis of Platinum Single-Atom Catalysts for Hydrogen Evolution Reaction.
Nanomaterials (Basel)
January 2025
Department of Materials, School of Natural Science, The University of Manchester, Oxford Road, Manchester M13 9PL, UK.
Platinum (Pt)-based heterogeneous catalysts show excellent performance for the electrocatalytic hydrogen evolution reaction (HER); however, the high cost and earth paucity of Pt means that efforts are being directed to reducing Pt usage, whilst maximizing catalytic efficiency. In this work, a two-step laser annealing process was employed to synthesize Pt single-atom catalysts (SACs) on a MOF-derived carbon substrate. The laser irradiation of a metal-organic framework (MOF) film (ZIF67@ZIF8 composite) by rapid scanning of a ns pulsed infrared (IR; 1064 nm) laser across the freeze-dried MOF resulted in a metal-loaded graphitized film.
View Article and Find Full Text PDFElectrocatalytic and Photocatalytic N Fixation Using Carbon Catalysts.
Nanomaterials (Basel)
January 2025
Institute of Materials Science & Devices, School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China.
Carbon catalysts have shown promise as an alternative to the currently available energy-intensive approaches for nitrogen fixation (NF) to urea, NH, or related nitrogenous compounds. The primary challenges for NF are the natural inertia of nitrogenous molecules and the competitive hydrogen evolution reaction (HER). Recently, carbon-based materials have made significant progress due to their tunable electronic structure and ease of defect formation.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!