Described here is the development of sequential cross-coupling, photoelectrocyclizations, and reductive dearomatizations of biaryl cyclohexenones as a means of synthesizing terpene skeletons. This methodology promises to provide insight that will enable us and others to use this approach to generate a variety of biologically active small molecules, including members of the abietane and morphinan skeletons.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10430876 | PMC |
| http://dx.doi.org/10.1016/j.tet.2022.133180 | DOI Listing |
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