Fabrication of 2D/1D BiWO/halloysite nanotubes photocatalyst towards water purification: a support effect onconstruction and electron-hole separation.

In this research work, a reusable and efficient 2D/1D heterogeneous structured photocatalyst based on amine-functionalized halloysite nanotubes (MHNTs) and BiWOnanosheet (BWO) was prepared using a facile hydrothermal method for decomposing PPCPs under simulated sunlight. On the degradation of tetracycline hydrochloride (TCH), the effects of composite catalysts prepared under various conditions were discussed. The results showed that over BWO/MHNTs with a mass ratio was 3:1, the synthesizing temperature was 120 °C and the precursor pH value was 1, the TCH (10 mg l) degradation efficiency reached 100% after 1 h irradiation of simulated sunlight. Moreover, BWO/MHNTs composites kept good recovery and stable photocatalytic activity after 5 cycles. The excellent dispersion of BiWOon the surface of clay minerals and the oxygen vacancy enhanced electron-hole separation may be responsible for the its high activity and stability. Futhermore, the radical capture test demonstrated that ·Owas primarily responsible for the photodegradation of TCH. Thus, BWO/MHNTs composites exhibit a good application prospect in the field of sunlight-driven photocatalytic degradation towards PPCPs pollutants in water.