There were limited researches on the scientific disposal of As-enriched plants, and how to reduce the available As content in the processed products and improve the utilization value were the key. In this study, the effect and mechanism of biochar produced by the As-enriched Pteris vittate before and after modification on the removal of As(III) in water were studied. The results indicated that the available As contents of Fe-BC300 and Fe-BC500 were reduced by 78.7 % and 91.9 % compared to original biochars, respectively. Modified biochars not only had a large adsorption capacity for As(III) (50.3 and 39.7 mg/g), but also can efficiently oxidize As(III) to As(V). The removal rate of As(III) by modified biochar was still higher than 50% after 3 cycles. The increase of the point of zero charge and the introduction of Fe were the main reasons for its efficient adsorption and oxidation of As(III).
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