Rational Multidimensional Shielded Multiple Resonance Emitter Suppresses Concentration Quenching and Spectral Broadening for Solution-Processed Organic Light-Emitting Diodes.

ACS Appl Mater Interfaces

Macao Institute of Materials Science and Engineering (MIMSE), Faculty of Innovation Engineering, Macau University of Science and Technology, Taipa 999078, Macao, People's Republic of China.

Published: August 2023

Thermally activated delayed fluorescence (TADF) emitters based on multiple resonance (MR) effects are promising for high-definition organic light-emitting diodes (OLEDs) with narrowband emission and high efficiency. However, they still face the challenges of aggregation-caused quenching (ACQ) and spectral broadening. Solution-processable MR-TADF emitters with an external quantum efficiency (EQE) of >20% and a full width at half-maximum (fwhm) of <30 nm have rarely been reported. To construct ACQ-resistant emitters without sacrificing color purity, the aggregation-induced MR-TADF material with a rigid B,N-containing polycyclic aromatic hydrocarbon core and four carbazole substituents as well as 12 -butyl groups on the periphery is designed. The multidimensional shielded effect largely limits the ACQ, intermolecular interactions, and spectral broadening. Consequently, solution-processed OLEDs based on exhibit a maximum EQE of 23.0% and high color purity with a fwhm of 25 nm. Furthermore, the nondoped device achieves a high efficiency (12.3%) and merely a slight widening of the fwhm to 27 nm. This work provides a feasible strategy to achieve MR-TADF materials with resistance to concentration quenching and high color purity.

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http://dx.doi.org/10.1021/acsami.3c07852DOI Listing

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