The reaction of homoleptic beryllium halide with diphenyl beryllium complexes leads to the clean formation of heteroleptic beryllium Grignard compounds [(L) BePhX] (X=Cl, Br, I; L=C-, N-, O-donor ligand). The influence of ligands and solvent on these compounds, their formation and exchange equilibria in solution were investigated, together with the factors determining the complex constitution.
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| http://dx.doi.org/10.1002/chem.202302495 | DOI Listing |
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