Recent progress on biodegradable polylactic acid based blends and their biocomposites: A comprehensive review.

Being less dependent on non-renewable resources as well as protecting the environment from waste streams have become two critical primers for a global movement toward replacing conventional plastics with renewable and biodegradable polymers. Despite all these efforts, only a few biodegradable polymers have paved their way successfully into the market. Polylactic acid is one of these biodegradable polymers that has been investigated thoroughly by researchers as well as manufactured on a large industrial scale. It is synthesized from lactic acid obtained mainly from the biological fermentation of carbohydrates, which makes this material a renewable polymer. Besides its renewability, it benefits from some attractive mechanical performances including high strength and stiffness, though brittleness is a major drawback of this biopolymer. Accordingly, the development of blends and biocomposites based on polylactic acid with highly flexible biodegradable polymers, specifically poly(butylene adipate co terephthalate) has been the objective of many investigations recently. This paper focuses on the blends and biocomposites based on these two biopolymers, specifically their mechanical, rheological, and biodegradation, the main characteristics that are crucial for being considered as a biodegradable substitution for conventional non-biodegradable polymers.