We report a topological phase transition in quantum-confined cadmium arsenide (Cd_{3}As_{2}) thin films under an in-plane Zeeman field when the Fermi level is tuned into the topological gap via an electric field. Symmetry considerations in this case predict the appearance of a two-dimensional Weyl semimetal (2D WSM), with a pair of Weyl nodes of opposite chirality at charge neutrality that are protected by space-time inversion (C_{2}T) symmetry. We show that the 2D WSM phase displays unique transport signatures, including saturated resistivities on the order of h/e^{2} that persist over a range of in-plane magnetic fields. Moreover, applying a small out-of-plane magnetic field, while keeping the in-plane field within the stability range of the 2D WSM phase, gives rise to a well-developed odd integer quantum Hall effect, characteristic of degenerate, massive Weyl fermions. A minimal four-band k·p model of Cd_{3}As_{2}, which incorporates first-principles effective g factors, qualitatively explains our findings.
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http://dx.doi.org/10.1103/PhysRevLett.131.046601 | DOI Listing |
Mater Horiz
January 2025
Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong, 2500, Australia.
Recently, the emergence of two-dimensional (2D) multiferroic materials has opened a new perspective for exploring topological states. However, instances of tuning topological phase transitions through ferroelectric (FE) polarization in 2D ferromagnetic (FM) materials are relatively rare. Here, we found that 11 single layer (SL) materials, named the MMGeX family, possess both FE and FM properties.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
State Key Laboratory of Solidification Processing, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, China.
Two-dimensional (2D) nanomaterials have garnered extensive attention owing to their unique properties and versatile application. Here, a family of 2D rare-earth metal phosphides (MP, M = Sc, Y, La) and their derivatives MPOT (T = F, OH) is developed to find their topological and electronic properties on the basis of density functional theory simulations. We show that the 2D MP compounds are most possibly obtained from thermodynamically stable MInP by chemical exfoliation.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
State Key Laboratory of Reliability and Intelligence of Electrical Equipment, and School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China.
Inorg Chem
December 2024
School of Physical Science and Technology, Northwestern Polytechnical University, Xian 710072, China.
In this paper, we have performed a crystal structure screening and properties prediction framework within the noncentrosymmetric AMX system, which arises from the intercalation of elements in transition metal dichalcogenides. After rigorous evaluations of thermodynamic and dynamic stability, we have refined our initial structure pool of 504 crystals to a focused set of 48 promising candidates. Analysis of their electronic properties has revealed that 23 of these crystals exhibit semiconducting behavior.
View Article and Find Full Text PDFJ Phys Condens Matter
November 2024
Department of Electronic Science and Engineering, Tianjin Key Laboratory of Efficient Utilization of Solar Energy, Engineering Research Center of Thin Film Optoelectronics Technology (Ministry of Education), Nankai University, Tianjin 300350, People's Republic of China.
Realizing novel two-dimensional (2D) magnetic states would accelerate the development of advanced spintronic devices and the understandings of 2D magnetic physics. In this paper, we have examined the magnetic and electronic properties of 20 dynamically stable and exfoliable MXO (M = Ti-Ni; X = S-Te; excluding CoTeO). It has been unveiled that [XO]-and [M]-crystal fields govern the M-3orbital splittings in MXO.
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