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The exploration of transition metal oxynitrides has garnered significant interest due to their intriguing property diversity. Herein, we present a promising new transition metal oxynitride BaLaVON, which features an anti-perovskite structure type. This unique structural configuration endows the material with remarkable conductivity, particularly at low temperatures, paving the way for the material to be used in a wide range of technological applications.
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http://dx.doi.org/10.1039/d3cc02785f | DOI Listing |
J Am Chem Soc
December 2024
State Key Laboratory and Institute of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Tianjin 300071, China.
The exploration of main group compounds with multiple bonds has significantly enhanced our understanding of chemical bonding and expanded transition-metal-free bond activation and catalysis. Diborynes, characterized by a boron-boron triple bond (B≡B), represent a particularly challenging area due to boron's limited valence electrons. Here, we report the synthesis and characterization of a silylene-stabilized diboryne (), expanding the frontier of diboryne stabilization.
View Article and Find Full Text PDFHuan Jing Ke Xue
January 2025
State Key Laboratory of North China Crop Improvement and Regulation, Key Laboratory of Ecological Environment of Farmland in Hebei, College of Resources and Environmental Sciences, Hebei Agricultural University, Baoding 071000, China.
To clarify the characteristics of Cd, As, and Pb concentrations in edible parts of crops and farmland soils, a key farmland survey was conducted on the field scale to investigate the characteristics of Cd, As, and Pb in soil and chili pepper (edible parts in the above-ground section) and sweet potato (edible parts under the ground) and assess the health risk of Cd-As-Pb in edible parts of chili pepper and sweet potato to humans in the typical co-contaminated agricultural soils by Cd, As, and Pb from metal smelting and sewage irrigation in North China. The results showed that the agricultural soil from chili pepper and sweet potato fields was co-contaminated by Cd and As at a moderate pollution level. The combined pollution index (2.
View Article and Find Full Text PDFHuan Jing Ke Xue
January 2025
College of Resources and Environment, Yunnan Agricultural University, Kunming 650201, China.
The nitrogen cycle has an important impact on the element cycle of the soil ecosystem. Moreover, it is important to clarify the key environmental factors of nitrogen cycle microorganisms for ecological restoration in mining areas. The functional flora can regulate the growth of vegetation by participating in the biogeochemical cycle of soil elements in the mining area, which is beneficial to the reclamation of the mining area.
View Article and Find Full Text PDFHuan Jing Ke Xue
January 2025
State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200082, China.
As emerging contaminants, antibiotic-resistant bacteria (ARBs) and antibiotic-resistant genes (ARGs) pose a serious threat to human health and ecological security. Here, a reduced graphene oxide and g-CN co-doped copper ferrite (rGO-CNCF) were synthesized. The composite material was characterized using XRD, FTIR, XPS, SEM-EDS, TEM, and DRS analysis methods, and a visible-light-assisted rGO-CNCF-activated PMS system was constructed for the removal of ARB and ARGs in water.
View Article and Find Full Text PDFAnal Chem
December 2024
Department of Chemistry, National Chung Hsing University, Taichung City 402202, Taiwan, ROC.
Four-dimensional printing (4DP) technologies can expand the functionality of stimuli-responsive devices to enable the integration of multiple stimuli-responsive parts into a compact device. Herein, we used digital light processing three-dimensional printing technique, flexible photocurable resins, and photocurable resins of the temperature-responsive hydrogels comprising -isopropylacrylamide (NIPAM), ,'-methylenebis(acrylamide) (MBA), and graphene for 4DP of a lab-on-valve (LOV) solid-phase extraction (SPE) device. This device featured flow manifolds and a monolithic packing connected by four near-infrared (NIR)-actuated temperature-responsive switching valves composed of a poly(NIPAM/MBA) (PNM) ball pushing a flexible membrane.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!